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  • 1965-1969  (1)
  • 1945-1949  (3)
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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry 39 (1947), S. 830-837 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Solar physics 9 (1969), S. 397-419 
    ISSN: 1573-093X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Hydrostatic models of sunspot penumbra and umbra are evaluated using Bode's tables of monochromatic absorption coefficients andT-τ-relations given by Makita and Morimoto (1960) and by Zwaan (1965). These models are placed side by side to simulate a complete sunspot corresponding to an area of 480×10−6 of a hemisphere. Intensity profiles are evaluated for aspect angles up to 85° and compared to observations. The primary aim was to study the influence of spot transparency, which is closely related to the gas-pressure, on the Wilson-effect and on other changes in the intensity profile that appear close to the solar limb. The gas-pressures at the zero-level in the geometrical depth (z=0) corresponding to optical depth, τ=10−3, both in the umbra,P 0 u , and in the penumbra,P 0 p , appear as adjustable parameters. When curvature is taken into account, the Wilson-effect cannot be reproduced without depressing the zero-point in the geometrical scale in the umbra relative to the same layer in the photosphere. A depression of 400 km will give a reasonably good fit for the Wilson-effect providedP 0 u 〈P 0 P 〈P 0 Ph . The model we found to give the best fit is based on Makita and Morimoto'sT-τ-relations withP 0 P =3200 andP 0 u =800. We have here chosen an umbra pressure that gives a small limb-side intensity peak at the penumbra border, assuming that the bright points described by Bray and Loughhead (1964) may be interpreted in terms of a transparency effect. Other parameters measured by Wilson and Cannon (1968) are evaluated, and for some a good agreement was obtained, while for others only a qualitative effect in the same direction could be found. Surfaces along which the optical path is constant (isodiaphanous surfaces) are functions of aspect angle and well suited for visualizing the transparency in spots. It is shown how for a wide range of models the isodiaphanous surfaces get asymmetric close to the limb. This has consequences for the interpretation of the Evershed-effect. In fact, under certain conditions, a ‘masking’ effect may take place because the greater transparency in the penumbra will allow observations of a deep laying flow, which will not be visible through the more opaque photosphere. Due to the asymmetry this effect is different on the limb side and the center side. We also found the spot to show an apparent displacement away from the limb, which at a heliocentric distance of 85° amounts to about one second of arc. Intensity profiles in the near infrared at 8206 Å and at 16482 Å are evaluated, and the importance of observations in these spectral regions is emphasized.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 32 (1949), S. 1326-1333 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Bereitung des δ5;14;16-3β-Acetoxy-ätiocholatriensäure-methylesters (V) auf zwei verschiedenen Wegen wird beschrieben. Die Behandlung dieses Esters V mit Phtalmonopersäure und Adsorption der Oxydationsprodukte an Aluminiumoxyd führt zu 5 verschiedenen Verbindungen, für die auf Grund ihrer charakteristischen physikalischen Daten und ihres Verhaltens bei der Chromatographie die Konstitutionsformeln IV, VI, VII, VIII und IX vorgeschlagen werden.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 32 (1949), S. 1334-1340 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die künstliche Bereitung einer 3,5,14-Trioxy-ätiosäure (vgl. IX) der Steroid-Reihe wird beschrieben. Die sterischen Verhältnisse an den Asymmetriezentren 3,5,14 und 17 dieser Verbindung werden diskutiert. Ein Vergleich dieses partialsynthetischen Steroids mit bekannten Abbauprodukten aus Periplogenin und allo-Periplogenin bestätigt die heute für diese Aglykone angenommene Struktur.
    Type of Medium: Electronic Resource
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