ISSN:
1612-1112
Schlagwort(e):
Column liquid chromatography
;
Photokinetic data
;
Reaction mechanism
;
(E)-1-phenylpropene
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Summary A combined method of high-performance liquid chromatography and UV-absorption spectroscopy is described for use in dynamic systems. It provides a way of obtaining detailed mechanistic information as well as quantitative data (rate constants, quantum yields), even though neither mechanism nor photoproducts are known. The kinetic treatment of the photoreaction of (E)-1-phenylpropene was successful, showing a photo-isomerization and a parallel step. Information on this additional step is obtained by using HPLC to observe the changes in the concentrations of the reactants' selectivity. The necessity of process control is demonstrated.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF02311813
Permalink