ISSN:
0360-6376
Schlagwort(e):
Physics
;
Polymer and Materials Science
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The Kelen-Tüdös linear graphical method was used to determine the copolymerization parameters of some halogen-substituted (e.g., Cl, Br, I) aniline monomers. It was found during copolymerization with p-aminobenzoic acid or p-aminophenol that the reactivity of these monomers followed the order of their basic strength. The order of their basic strength. The order of their reactivity, however, was reversed if they copolymerized with sulfanilic acid (SA). This reversal has been interpreted in terms of the resonance stabilization of monomers, the nature of the acidic functional groups present in the comonomer, and the influence of electron-accepting or electron-donating groups present in the comonomers.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/pol.1983.170210423
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