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  • 1
    ISSN: 1432-0649
    Keywords: 42.60 ; 34.50
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Saturation of two-dimensional laser-induced fluorescence is demonstrated using the coincidence between the strong 0–0 vibrational transition of OH around 308 nm and the emission of a tunable XeCl excimer laser. The 2D images were insensitive to variations in the laser power, implying reduced sensitivity to quenching processes. The ratio of the 2D images in the linear and saturated regimes show two-dimensional variations in the saturation intensity. Since saturation intensity is proportional to the quenching rate, this novel method allows one to check for variations in collisional lifetimes across the flame.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0649
    Keywords: 42.55.Px ; 42.62.Fi ; 07.65.Gj
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present an optically stabilized lead-salt diode-laser system which is the nucleus of a very-high-resolution instrument for sub-Doppler molecular spectroscopy in the mid-infrared. By application of external optical feedback, we have narrowed the diode-laser linewidth by two orders of magnitude, yielding a spectral width of less than 200 kHz. The diode- laser frequency is stabilized and controlled via the external reflector by variable-frequency offset-locking the diode-laser to a CO laser frequency. This substantial improvement in the spectral properties enabled us to perform a Lamb-dip experiment on a carbonyl sulfide (OCS) absorption line near 1985 cm−1. We were able to detect a saturated dispersion signal at low pressure (5 Pa) with a signal-to-noise ratio of several thousand. The present paper describes the unique features of the optically stabilized tunable diode-laser system and its use as a spectroscopic tool for sub-Doppler applications.
    Type of Medium: Electronic Resource
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