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  • 25.70.Jj  (3)
  • Inhibitors  (2)
  • 1
    ISSN: 1434-0879
    Keywords: Calcium oxalate ; Heterogeneous nucleation and growth ; Inhibitors ; Pyrophosphate ; Hydroxyapatite
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary The nucleating effect of hydroxyapatite (HAP) and the inhibitory effect of pyrophosphate (PPi) on calcium oxalate crystallization have been studied at different pH's in solution metastabely supersaturated with respect to calcium oxalate but saturated with respect to HAP. Crystallization was monitored by a decrease of calcium in the supernatant and formation products were calculated. At a pH above 6.0 already minimal HAP concentrations proved to be a suitable substrate for heterogeneous nucleation and growth of calcium oxalate. PPi showed a pronounced inhibitory effect on spontaneous as well as on HAP induced crystallization of calcium oxalate, this effect being highly pH dependent. HAP was found to neutralize the inhibitory effect of PPi in a molar ratio of 10:1.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Urological research 18 (1990), S. 219-222 
    ISSN: 1434-0879
    Keywords: Inhibitors ; Calcium-oxalate monohydrate growth ; Pyrophosphate ; Citrate ; Urine
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary In order to have a rapid method of measuring the inhibition of calcium-oxalate monohydrate growth in freshly voided whole urine, a test system by Meyer and Smith that has originally been developed for diluted urine was modified. The crystallization processes were monitored by an ion-selective calcium electrode, which allowed determination of the half-life value of the decrease in calcium within 25 min. Even given the high inhibitory activity of whole urine, the test gave reliable results when a high seed concentration was used. Inhibition was expressed as the ratio between the half-lives of the calcium decrease obtained in the presence and in the absence of inhibitors. This approach allowed kinetic studies of individual inhibitors in model solutions. Furthermore, the measurements of inhibitors in urine could be, performed before the chemical composition was determined.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1434-601X
    Keywords: 25.70.Jj ; 25.70.Gh ; 27.90.+b
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The fusion of the massive systems110Pd+104Ru and110Pd+110Pd was uniquely identified by observing the a decay of the evaporation residues. The observed distribution of the fusion cross section on the different evaporation-residue channels is in clear contradiction to calculations based on the compound-nucleus model. As a possible explanation the precompound evaporation of a particles is proposed.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1434-601X
    Keywords: 25.70.Gh ; 25.70.Jj
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Velocity distributions of heavy residuesA Res〉A tar,Z Res〉Z tar identified by means ofα spectroscopy, have been investigated at the velocity filter SHIP in reactions20Ne+208Pb at projectile energies E/A=8.6, 11.4 and 15.0 MeV/u. Besides products from complete or nearly complete fusion, characterized by velocity distributions peaking atν/ν CN≅0.8–1.0, heavy residues with mean velocities of about half of the compound nucleus velocity were observed. The Z-distribution of this component was found to peak atZ=87. It is interpreted as residues from fusion of target nuclei with projectile fragments produced by nearly symmetric break-up. The experimental results were compared with predictions of theoretical models: cross sections for incomplete fusion were calculated using the sum-rule model of Wilcynski et al., while residue cross sections were calculated using the evaporation code HIVAP. A fair agreement between experimental and calculated mass distributions of heavy residues and transferred projectile fragments is achieved if an energy dissipation of ≅23% (at E/A=8.6 MeV/u) and ≅8% (at E/A=11.4 MeV/u) of the incident projectile energy is introduced. The observed peak of theZ-distribution atZ=87 is predominantly effected due to a higher fission probability of products withZ〉87 during the deexcitation process and experimental limitations in the identification of products withZ≦86 by means of a spectroscopy, which cause a decrease of the observed production rates towards lowerZ.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 343 (1992), S. 301-307 
    ISSN: 1434-601X
    Keywords: 25.70.Gh ; 25.70.Jj
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Evaporation residue cross sections have been measured in reactions40Ar +140Hf,181Ta,182W,184W,natRe at bombarding energiesE/A=(5.5–6.3) MeV/u. The cross sections do not decrease with increasing nuclear temperature, as expected from statistical model calculations. Rather they are found to be roughly constant. This behavior is predominantly affected by an enhanced emission probability of charged particles. Influence of a ‘fission delay’, which is expected atE x〉60 MeV from measurements of pre- and post-scission neutrons, on thexn- cross sections has been observed at excitation energiesE x〉90 MeV. The possibility to produce transfermium isotopes in ‘hot fusion’ reactions has been investigated in an irradiation of232Th with40Ar. Upper limits of 10 nb for evaporation residues were obtained.
    Type of Medium: Electronic Resource
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