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  • Ammonia loss  (2)
  • Analytical Chemistry and Spectroscopy  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of atmospheric chemistry 6 (1988), S. 133-147 
    ISSN: 1573-0662
    Keywords: Ammonia loss ; energy balance ; micrometeorology ; water-air transfer
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Vertical flux densities of ammonia, water vapour and sensible heat were measured over a flooded rice field in China following the application of ammonium bicarbonate fertilizer. Aqueous and gaseous phase transfer resistances for ammonia were deduced from these measurements. The aqueous phase resistance was maximal in the morning and least in the afternoon. Stable stratification of the floodwater immediately adjacent to the air-water interface was observed during the morning when evaporation rates were low, and may be responsible for inhibiting the transfer of ammonia to the atmosphere.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-0867
    Keywords: Ammonia loss ; denitrification ; nitrogen balance ; algal growth ; transfer processes
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract Losses of nitrogen were investigated after applications of ammonium bicarbonate and urea to flooded rice at transplanting. Ammonia (NH3) volatilization was determined by direct micrometeorological methods, and total loss of fertilizer nitrogen (N) was measured by15N balance. All the loss appeared to be in gaseous forms, since there was no evidence of leaching and runoff was prevented. The difference between N loss and NH3 loss was thus assumed to be denitrification loss. Both NH3 volatilization and denitrification losses were large, being 39% and 33%, respectively, of the ammonium bicarbonate N, and 30% and 33%, respectively, of the urea N applied by farmers' methods. Ammonia fluxes from the field fertilized with ammonium bicarbonate were very high for two days, and then declined rapidly as the NH3 source in the floodwater diminished. Moderate fluxes from the field fertilized with urea continued over 6 days, but calculations showed that NH3 transfer from floodwater to atmosphere was retarded during the middle period of the experiment, particularly on day 2 when a thick algal scum appeared on the water surface. The results indicate that this algal mass obstructed the transport of NH3 across the water-air interface until the scum was dispersed by wind action. Nevertheless, the prolonged NH3 losses on the urea treatment were due primarily to high floodwater pH values promoted by the strong algal growth during the daylight hours. Nitrogen-15 balance studies showed that incorporation of fertilizer into drained soil substantially increased recoveries of fertilizer N in rice plants and soil compared with incorporation of fertilizer in the presence of standing floodwater. Ammonia loss measurements on these treatments when urea was applied suggested that the improvement in fertilizer N efficiency was due mainly to reductions in NH3 loss.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 11 (1988), S. 395-400 
    ISSN: 0935-6304
    Keywords: Gas chromatography (GC) ; Fused silica ; Column technology ; Surface modification ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method has been developed for fabricating fused silica capillary columns which have specific surface properties but still retain the excellent strength, flexibility, and resilience of pure fused silica. By using the Modified Chemical Vapor Deposition process (MCVD), typically used for the production of optical fiber lightguides, inorganic dopants such as Al, Nd, Ge, and P can be introduced into the preform-tube by MCVD. Doped columns have a wide range of specific surface properties, and columns with undoped fused silica prepared by MCVD are more chemically inert and less acidic than columns prepared by conventional methods. This paper describes the method for fabricating capillaries and the initial studies to characterize them.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In a number of infectious and inflammatory diseases, stimulation of the immune system can lead to increased accumulation of tryptophan metabolites via induction of kynurenine pathway enzymes in extrahepatic tissues. We developed a liquid chromatographic/mass spectrometric (LC/MS) method suitable for tracing the disposition of 13C isotopomers of L-tryptophan and L-kynurenine in various cultured cell, tissue slice, and whole animal model systems used to investigate tryptophan flux through the kynurenine pathway. The method employs extractive derivatization of the analytes and their 2H internal standards with pentafluorobenzyl bromide in order to enhance the negative ion chemical ionization (NICI) mass spectrometric response. Normal-phase liquid chromatographic separation of derivatized analytes was optimized using a silica column with organic solvents, followed by particle beam transfer and NICI-MS. Standard curves were linear over the range 1-250 ng per sample. Particle beam and mass spectrometric operating parameters were optimized with direct flow injections of 1-(methylamino) anthra-quinone, which is an ideal test compound for the evaluation of LC/NICI-MS. The developed method was used to quantify the conversion of (13C6)L-tryptophan to (13C6)L-kynurenine by human monocytes (THP-1) stimulated with interferon-γ, lung and brain tissue slices obtained from gerbils immune-stimulated with pokeweed mitogen. The effect of whole body immune stimulation on the plasma levels of engogenous L-kynurenine in mice stimulated with interferon-γ was also quantified.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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