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  • infrared  (4)
  • Analytical Chemistry and Spectroscopy  (3)
  • 1
    Electronic Resource
    Electronic Resource
    The crystal structure and IR spectra of μ-(bipyrimidine-N1,N1′,N5,N5′)-bis[(azido-N1)(methanol)(bipyrimidine-N1,N1′)copper(II)] bis(triflate) bis(methanol) (1998)
    Springer
    Journal of chemical crystallography 28 (1998), S. 427-432 
    Details
    ISSN: 1572-8854
    Keywords: Dinuclear ; copper ; triflate ; bipyrimidine ; azido ; infrared
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of the title compound [Cu2(bipym)3(N3)2(CH3OH)2](CF3SO3)2(CH3OH)2 has been determined by X-ray diffraction. The crystals are triclinic, space group P1, with a = 8.1844(5), b = 11.0253(6), c = 12.9089(7) Å, α = 80.249(4), β, = 74.933(5), γ = 74.001(4)°, and Z = 1. The structure consists of a dinuclear Cu(II) unit formed of two didentate bipym ligands, one bis-didentate bipym ligand, two azido anions, and two coordinating methanol molecules. The Cu(II) atom is elongated tetragonally surrounded by two nitrogens of the didentate bipym ligand, one nitrogen of the bis-didentate ligand, and one nitrogen of the azido anion forming the equatorial plane with one nitrogen of the bis-didentate ligand and an oxygen atom of the methanol molecule as the axial atoms. A noncoordinating triflate anion and an additional methanol molecule are also in the crystal lattice and have a hydrogen bond distance of 2.801(3) Å with an angle of 157(4)°. The cations link by O – H ··· N bonds into infinite chains running in the c-direction.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1021760420238
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  • 2
    Electronic Resource
    Electronic Resource
    Crystal structure and spectroscopy of bis-[bis(2-benzimidazolyl)propane]copper(II) bis(triflate)monohydrate, a copper complex with a geometry intermediate between tetrahedral and square planar (2000)
    Springer
    Journal of chemical crystallography 30 (2000), S. 793-797 
    Details
    ISSN: 1572-8854
    Keywords: copper ; bis(benzimidazoles) ; crystal structure ; infrared
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The structure of a mononuclear copper(II) compound with the ligand bis(2-benzimidazolyl)propane (abbreviated as tbz) is reported. The compound [Cu(tbz)2](CF3SO3)2(H2O) crystallizes in the triclinic space group P $$\bar 1$$ , with a = 12.363(6), b = 13.218(9), c = 15.365(8) Å, α = 82.74(5), β = 68.04(4), γ = 65.30(5), and Z = 2. The Cu(II) atom has a geometry intermediate between tetrahedral and square planar, consisting of four nitrogen atoms of two tbz ligands. The Cu—N—Cu angles are about 135°, while the dihedral angle between them amounts to 62° (0° for square planar and 90° for a tetrahedron). Ligand field bands are observed at 10.2 × 103, 13.8 × 103, and 20.3 × 103 cm−1, while the most characteristic infrared vibrations of the triflate anion are observed at 1273, 1260, 1238, 1221, 1171, and 1157 cm−1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1013276325343
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  • 3
    Electronic Resource
    Electronic Resource
    Synthesis, spectroscopy, and X-ray structure of the polymer catena-[bis(azido-N)-copper(II)-μ-bis(2-benzimidazolyl)butane] (2000)
    Springer
    Journal of chemical crystallography 30 (2000), S. 69-72 
    Details
    ISSN: 1572-8854
    Keywords: azido ; crystal structure ; copper(II) ; infrared ; polymeric
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The title compound, catena-[bis(azido-N)-copper(II)-μ(bis(2-benzimidazolyl)butane), [Cu(C18H18N4)(N3)2]n, was obtained from the reaction of the ligand bis(2-benzimidazolyl)butane and Cu(N3)2. The x-ray crystal structure is reported. The compound crystallizes in the monoclinic space group P21/c with a = 8.2524(10), b = 12.765(5), c = 9.1125(15) Å, β = 106.423(12)°, Z = 2. The Cu(II) ions are square-planar coordinated with trans-oriented end-on binding azido ligands. The structure is a polynuclear chain with the benzimidazole bridging at each end. In addition a N(ligand)-H···N(azido) H-bridge [N(ligand)···N(azido) = 2.994(7) Å] is present, resulting in a pseudo 2-dimensional lattice. The characteristic azido infrared vibrations are found at 2060 and 2077 cm−1 (νas(N3)) and 1284 and 1297 cm−1 (ν(N3)).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1009506418398
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  • 4
    Electronic Resource
    Electronic Resource
    Crystal structure and spectroscopy of the low-spin iron(II) compound: tris(bipyrimidine)iron(II) bis(triflate), [Fe(bipym)33](CF3SO3)2 (2000)
    Springer
    Journal of chemical crystallography 30 (2000), S. 441-444 
    Details
    ISSN: 1572-8854
    Keywords: 2,2′-Bipyrimidine ; low-spin ; iron ; crystal structure ; infrared
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Notes: Abstract The compound [Fe(bipym)33](CF3SO3)2 (in which bipym = 2,2′-bipyrimidine) crystallizes in the space group P21/c, with a = 13.7641(11), b = 18.7557(19), c = 12.3627(11) Å, β = 103.085(8)° and Z = 4. The low-spin Fe(II) atom is octahedrally surrounded by six nitrogen atoms of three bipyrimidine groups with Fe—N distances that vary from 1.968(4) to 1.975(4) å. In the far-infrared region the Fe—N vibrations are observed at 359 and 372 cm-1.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1023/A:1011339214337
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  • 5
    Electronic Resource
    Electronic Resource
    A study of the electron impact-induced fragmentation of 1,6-diaminohexane (1976)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 11 (1976), S. 995-1001 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectrometric behaviour of 1,6-diaminohexane has been studied with the help of deuterium labelling in every position of the molecule. Extensive intramolecular exchange reactions between the hydrogen atoms of the amino groups and those of the hydrocarbon chain are responsible for the apparent complexity of the fragmentation mode.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210110912
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  • 6
    Electronic Resource
    Electronic Resource
    A study of the fragmentation of cyclopentane-1,3-diols and of cyclopentane-1,2,4-triols (1975)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 10 (1975), S. 702-710 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mass spectra of the two cyclopentane-1,3-diol and of the three cyclopentane-1,2,4-triol stereoisomers have been studied. Extensive deuterium labelling allows the detection of complex processes, especially for the elimination of water from the [M - H2OO]+· and [M]+· ions.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210100904
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  • 7
    Electronic Resource
    Electronic Resource
    A new surface roughening method for glass capillary columns. Sodium chloride deposition from suspension (1979)
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 2 (1979), S. 447-455 
    Details
    ISSN: 0935-6304
    Keywords: Gas chromatography ; Capillary, glass ; Surface roughening by direct deposition of suspension particles ; NaCl used ; High reproducibility when coated with polar phases ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method is described for roughening the surface of glass capillary columns for subsequent coating with polar stationary phases. A suspension of sodium chloride, obtained by addition of a saturated solution of sodium chloride in methanol to 1,1,1-trichloroethane, is passed through the column at velocities of 1-5 cm/s. During passage of the suspension, particles of sodium chloride deposit spontaneously on the column wall. The amount of sodium chloride deposited on the column wall is a function of the volume of the suspension passed through and of the contact time of the suspension and the column wall. Ultimately the amount of sodium chloride per unit surface area approaches a maximum. Columns covered with this maximum amount of sodium chloride were prepared with high reproducibility and coated with a number of polar stationary phases. Various factors that influence the stability of the suspension and the deposition of sodium chloride are discussed and minimum requirements are given. A theoretical model is proposed for the mechanism of deposition of sodium chloride particles on the glass wall.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jhrc.1240020715
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