ISSN:
1052-9306
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Measurements of the dissociative ionization cross-sections of CO, CO2, NO and N2O molecules for electrons from 20 up to 1000 eV were performed. Total collection of ions was achieved by using a specially constructed cycloidal mass spectrometer, an ion source without slit and a collector with large area. In that open ion source the effusion molecular beam formed by a capillary was crossed by the electron beam. Owing to such parameters of the mass spectrometer the mass discrimination effects were reduced. At the ionization of CO molecules, the ions CO+, C+, O+ and CO2+ were registered; at CO2, the ions CO2+, CO+, O+, C+ and CO22+; at NO, the ions NO+, N+, O+ and NO2+; at N2O, the ions N2O+, NO+, N2, O+, O+, (N+, N2+ 2) and N2O2+. The relative values of the partial cross-sections were normalized to the absolute total ionization cross-sections obtained by Rapp and Englander-Golden.
Additional Material:
10 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/bms.1200160181
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