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Resonance in the Raman scattering of CaF2, SrF2, BaF2 and diamond (1981)

Grimsditch, M. ; Cardona, M. ; Calleja, J. M. ; [et al.]

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 10 (1981), S. 77-81

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ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The dependence of the first order Raman scattering efficiency of CaF2, SrF2, BaF2 and diamond on photon energy ωL has been measured with different techniques. We find that in the visible these cross-sections increase with ωL much faster than ωL4. This result has important implications as CaF2, for instance, is usually used as a standard scatterer in resonant Raman experiments, with the assumption that its efficiency is excatly proportional to ωL4. The possible sources of these anomalies are discussed.

Additional Material: 4 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250100113

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