ISSN:
1432-2234
Keywords:
Rydberg states
;
Atomic wavefunctions
;
Lithium atom
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The transition energies and singly excited P, D and F states of Li, Be+ and B2+ for the Rydberg levels 1s 22s: 2 S→1s 2 nl: 2L (n=5, 6,...9) have been calculated using time dependent coupled Hartree-Fock (TDCHF) theory. Within single particle model the theory includes RPA type correlations and furnishes reasonable description of the excited states. The transition energies and oscillator strengths for allowed transitions are in good agreement with the experimental and theoretical values, wherever available. Effective quantum numbers have been estimated for all transitions.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00526292
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