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  • 34D30  (1)
  • Baker-Venkataraman rearrangement  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of dynamics and differential equations 5 (1993), S. 417-467 
    ISSN: 1572-9222
    Keywords: Strong inclination property ; neutrally twisted homoclinic orbits ; cusp horseshoe maps ; quotient symbolic systems ; singular perturbations ; 00A71 ; 34A34 ; 34C28 ; 34D30 ; 58F12 ; 58F13 ; 58F14 ; 58F40
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mathematics
    Notes: Abstract Chaotic dynamics arises when the unstable manifold of a hyperbolic equilibrium point changes its twist type along a homoclinic orbit as some generic parameter is varied. Such bifurcation points occur naturally in singularly perturbed systems. Some quotient symbolic systems induced from the Bernoulli symbolic system on two symbols are proved to be characteristic for this new mechanism of chaos generation. Combination of geometrical and analytical methods is proved to be more fruitful.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1997 (1997), S. 2169-2175 
    ISSN: 0947-3440
    Keywords: Baker-Venkataraman rearrangement ; 3-Methoxyflavones ; Phase-transfer catalysis ; Catalytic transfer hydrogenation ; Transesterifications ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Some 3-methoxyflavones were known to possess antipicornavirus properties. In order to study the structure-activity relationship, attempts to prepare 3-methoxyflavone by literature methods were unsuccessful. We have modified the Baker-Venkataraman rearrangement, using a solid base and a phase-transfer catalyst. After searching optimal reaction conditions and a study of the intermediate formed in a model reaction, good yields were obtained for the 3-methoxyflavones 7, 21-32. Further some of the corresponding 7-O-n-butyl derivatives 4, 33-37 could be isolated as side products.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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