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  • 1
    ISSN: 1572-879X
    Keywords: Titanium silicalite ; oxidation catalyst ; hydrogen peroxide adsorption ; IR ; DRS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Titanium silicalites synthesized via different procedures are tested in the oxidation of phenol, l-octene and n-hexane by aqueous H2O2. It is shown that the presence of titanyl groups, on which H2O2 is activated by formation of titanium peroxo complexes, is a prerequisite for oxygenation activity. Furthermore, in order to afford high selectivities, titanium silicalites should be free of impurities which cause acid catalyzed side reactions or H2O2 decomposition.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1435-1536
    Keywords: IR ; ultrathin films ; LB films ; amphiphilic polymer ; microgel
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Molecular orientation and structure in five-monolayer Langmuir-Blodgett (LB) films of an amphiphilic polymer consisting of a flexible hydrophilic epichlorohydrinethylene diamine cross-linking microgels and a number of hydrophobic chains have been studied by infrared (IR) transmission and reflection-absorption (RA) spectroscopy. The downward shifts of the NH and C=O stretching bands show that the amide groups are involved in medium hydrogen bonds. A comparison of the band intensities between the transmission and RA spectra indicates that the hydrocarbon chains are nearly perpendicular to the substrate surface while the C-N bond of the amide group is nearly parallel to the surface. The vibrational frequencies of the two CH2 stretching bands suggest that the LB films have highly ordered alkyl chains.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1573-2932
    Keywords: surface sediments ; spatial distribution ; Chl a & c ; C, N & P ; bacterial activity ; Lake Kinneret
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The spatial variability of several sedimentological, chemical and biological parameters in the uppermost layer of bed sediment (ULBS) in Lake Kinneret, was studied during the development of anoxic conditions in the hypolimnion (May, 1995). ULBS samples were taken along a transect from the littoral to the pelagic zones, during the crash of the Peridinium gatunense bloom, about 2 months after the onset of stratification and when oxygen in the hypolimnion was almost completely depleted. The 2-3mm of the ULBS, collected by SCUBA diver, contained relatively fresh material (as shown by high Chl c content) but differed from that of intact Peridinium cells. In the ULBS, the C:N atomic ratio averaged 8 and was similar all over the lake bottom and the average Chlorophyll a:c ratio was 4 (reaching a value of ~7 at 5m). These ratios in Peridinium cells were about 14.3 and 2, respectively. In addition, δ 13C in the organic matter from the ULBS was lighter than that of Peridinium. This data suggests that substantial degredation of the organic matter already occurs in the water column. Grain size distribution suggests the occurance of intense focussing processes in Lake Kinneret. Chemical and biological parameters in the ULBS exhibited clear depth dependent patterns, suggesting changes in physical and chemical processes occur. Three different zones can be distinguished in Lake Kinneret bottom sediments. a. The littoral oxic photic zone (down to 5-7m), which is influenced by intensive biodegredation and high turbulence. b. Transition zone (7-20m), with an oxic-photic gradient and developed focussing processes. c. Profundal, anoxic zone (〉20m), where all fine, settled, organic rich material concentrates and undergoes anaerobic decomposition.
    Type of Medium: Electronic Resource
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  • 4
    ISSN: 1573-2932
    Keywords: surface sediments ; spatial distribution ; Chla &c ; C, N & P ; bacterial activity ; Lake Kinneret
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract The spatial variability of several sedimentological, chemical and biological parameters in the uppermost layer of bed sediment (ULBS) in Lake Kinneret, was studied during the development of anoxic conditions in the hypolimnion (May, 1995). ULBS samples were taken along a transect from the littoral to the pelagic zones, during tile crash of thePeridmium gatunense bloom, about 2 months after the onset of stratification and when oxygen in the hypolimnion was almost completely depleted. The 2–3mm of the ULBS, collected by SCUBA diver, contained relatively fresh material (as shown by high Chl c content) but differed from that of intactPeridinium cells. In the ULBS, the C:N atomic ratio averaged 8 and was similar all over the lake bottom and the average Chlorophyll a c ratio was 4 (reaching a value of ∼7 at 5m). These ratios inPeridinium cells were about 14 3 and 2, respectively. In addition, δ12C in the organic matter from the ULBS was lighter than that ofPeridinium. This data suggests that substantial degredation of the organic matter already occurs in the water column. Grain size distribution suggests the occurance of intense focussing processes in Lake Kinneret. Chemical and biological parameters in the ULBS exhibited clear depth dependant patterns, suggesting changes in physical and chemical processes occur. Three different zones can be distinguished in Lake Kinneret bottom sediments a. The littoral oxic pholic zone (down to 5–7m), which is influenced by intensive biodegradation and high turbulence. b Transition zone (7–20m), with anoxic-photic gradient and developed focussing processes c. Profundal, anoxic zone (〉20m), where all line, settled, organic rich material concentrates and undergoes anaerobic decomposition.
    Type of Medium: Electronic Resource
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