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  • Chemical Engineering  (2)
  • 1
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Electrical conductivity changes during thermal decomposition of several phenolic and silicone materials have been measured while increasing temperature from 25 to ∼ 700°C at a rate of 10°C per minute in a nitrogen atmosphere, The materials are based on phenolic and silicone resins and are reinforced with glass chopped fabric or cloth. The electrical results are correlated with mass loss and thermal decomposition product data obtained using mass spectroscopy and thermal gravimetric analysis. Peaks in the conductivity temperature dependence and deviations from ohmic behavior are found to be associated with material decomposition and/or outgassing. An excellent correlation is obtained between thermal stability and temperature-dependent electrical properties. Results suggest that electrical conductivity can be used as a thermal analytical tool in characterizing these materials.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 24 (1984), S. 435-441 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The high-temperature electrical conductivity and thermal decomposition characteristics of Sylgard® 184 with and without hollow microspheres of glass, silica, and ceramic have been determined to 600 to 700°C in air and nitrogen environments. The materials are silicone-based dielectrics and are used as electronic encapsulants. Results show that a peak in the conductivity temperature dependence at ∼300°C results principally from volatilization of [Si(CH3)2O]n with some evolution of water, that oxygen accelerates decomposition, and that the microspheres may help form a network of interconnected conductive pathways in the residual material. There is a good correlation between thermal stability and temperature-dependent electrical properties.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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