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  • 1
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 9 (1988), S. 229-236 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: High-impact polystyrene (HIPS) constitutes a mechanically attractive composite, consisting of a glassy matrix and a rubberlike particle phase (gel phase). Dynamic mechanical spectroscopy was performed for the polystyrene matrix for three different types of HIPS as well as for the concentrated gel-phase material, at the vicinity of the respective glass-transition temperatures (Tg). An approximate estimation of the gel-phase modulus was attempted by using known mechanical models. A comparison with experiments was also made. The modulus of the composite was found to be lower than the theoretical lower bound for particulate composites. This was attributed to a separate phase between gel particles and the matrix. A diffusion-type variation of the modulus of this mesophase layer was estimated, and a correlation between calculated fitting parametric exponents and impact behavior of HIPS was found. Moreover, the Tgs of the materials under investigation were also measured with two independent methods. It was found that all types of HIPS presented higher Tgs than the pure matrix by 5 to 10°C with the highest Tg found being that of the gel-enriched material. The shift of Tgs to higher temperatures was attributed to an eventual increase of the effective cross-link density of the matrix because of grafting.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Polymer Composites 7 (1986), S. 1-8 
    ISSN: 0272-8397
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The dynamic mechanical properties of composite materials, consisting of an epoxy matrix filled with iron particles, were determined over a temperature range. The storage- and loss moduli were evaluated in a Dynastat apparatus, with the parameters being the volume fraction of filler and the test frequency. A theoretical model was developed for comparing the experimental results with the theoretical predictions. A satisfactory correlation was obtained for the glassy region of the composite.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 28 (1988), S. 610-625 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The influence of the hard or soft inclusions and the mesophase layers in either a soft-hard-soft or hard-soft-hard combination of biphase plates submitted to dynamic tensile loads on the fracture mode and bifurcation process in both phases was investigated in this paper. It was assumed that the soft or hard matrix is infolding the hard or soft inclusion of the plate, so that the plate constitutes a meridional section of the representative volume element of a unidirectional fiber composite, or a principal section of a particulate. The influence of the mechanical properties of either phase on the crack propagation velocity and the initiation of crack bifurcation was studied by using high-speed photography and dynamic caustics. The results showed that the propagating crack tended to bifurcate either in the brittle or in the mesophase layer under certain conditions of propagation velocity. It was shown that bifurcation of a propagating crack depends on the elastic moduli and Poisson's ratios of the phases, as well as on the extent of the mesophase layer, which depended on the adhesion quality of phases.
    Additional Material: 17 Ill.
    Type of Medium: Electronic Resource
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