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Digitale Medien

Chromism of soluble polythienylenes (1987)

Rughooputh, S. D. D. V. ; Hotta, S. ; Heeger, A. J. ; [weitere]

Bognor Regis [u.a.] : Wiley-Blackwell

Journal of Polymer Science Part B: Polymer Physics 25 (1987), S. 1071-1078

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Details

ISSN: 0887-6266

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: Thermochromism and solvatochromism of solutions of poly(3-alkylthienylenes) are reported. The experimental results indicate the presence of two coexisting phases: polymer in solution and polymer in microcrystalline aggregates. From the concentration independence of the thermochromism, it is concluded that the transition is fundamentally driven by a single chain mechanism, and that the aggregation (microcrystallization) of the poly(3-alkylthienylene) macromolecules can occur only after the single chain conformational change has occurred.

Zusätzliches Material: 5 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/polb.1987.090250508

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