ISSN:
0021-8383
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
On the Telomerization of Isoprene at Low TemperatureThe telomerization of isoprene was carried out by means of a catalyst system of Pd(acac)2/PPh3 and complexes of the type Pd(acac)2 · L (L = PPh3; py; NHEt2) at 298 K. The reaction in methanol gave 8-methoxy-2, 7-dimethyl-octa-1, 6-diene (3a), 8-methoxy-3, 7-dimethyl-octa-1, 6-diene (4a) and oligomer products. 2, 7-Dimethyl-octa-1,3, 7-triene (1), 8-i-propoxy-2, 7-dimethyl-octa-1, 6-diene (3b) and oligomer products were obtained in i-PrOH. During the reaction a formation phase of the catalyst was observed.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/prac.19853270415
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