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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 33 (1995), S. 1125-1132 
    ISSN: 0887-624X
    Keywords: butadiene ; polymerization ; neodymium ; molecular weight ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The homopolymerization of 1,3-butadiene in a stirred batch reactor with the catalytic system Nd octoate/diethyl-aluminium chloride/triisobutyl-aluminium in n-heptane was studied. The effect of various reaction conditions on especially high conversion and molecular weight is reported. Polymerization is shown to be first order with respect to both monomer and neodymium. Molecular weights are high and broadly distributed. Chain transfer to triisobutylaluminium is the main factor governing molecular weight development. A mechanism of polymerization is presented with the chain transfer process incorporated. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 62 (1996), S. 835-844 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The preparation and adhesion properties of poly(methyl methacrylate-butyl acrylate)[P(MMA-b-BA)] diblock copolymers have been studied. Block copolymers were analyzed by 1H-NMR, DSC, and SEC, and confirm the synthesis of diblock copolymers, using the iniferter route. Investigation of peel strength in laminate joints, reinforced with various block copolymers, suggests that adhesion depends on both molecular weight and composition. When the copolymer contains mainly PMMA block, molecular weight has a marked effect, with adhesion being enhanced at higher copolymer molecular weight. For other PBA/PMMA compositions, no reinforcement was seen, irrespective of molecular weight. © 1996 John Wiley & Sons, Inc.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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