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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Chemometrics 3 (1989), S. 537-540 
    ISSN: 0886-9383
    Keywords: Cluster analysis ; Display ; Interlaboratory test ; Ultrametrics ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ultrametric inter-object distances found by hierarchical clustering may be used to generate and appropriate constellation of points in a plane. A configuration of points which reproduce the ultrametric distances in a low-dimensional space as closely as possible can be found by Torgerson's method of multidimensional scaling. The resulting display supports the cognition of clusters very well, and for this purpose it seems to be superior to, for instance, the frequently applied principal components display. In certain situations dedrograms are expected to become simpler to interpret when such complementary ‘cluster display’ is also consulted. An example from analytical chemistry is presented.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    ISSN: 1040-0397
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This work addresses the problem of signal resolution by partial least-squares regression (PLS) for differential pulse stripping voltammograms. The performance of PLS is demonstrated for an example of calibration with mixtures of two analytes (Tl+ and Pb2+) with strongly overlapping voltammograms. The accuracy of the determination of concentrations for validation mixtures was found to be considerably higher with PLS than with simple evaluation using currents observed at two potentials (requiring resolution of a system of two linear equations with two unknowns). Hence, PLS is recommended for computer-assisted, on-line voltammetric analysis of multicomponent systems.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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