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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 5 (1959), S. 37-46 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It is proposed that measurements of reaction rate as a function of position within turbulent flames be the basis of an approach to the problem of turbulent-flame propagation. As a test of the method, measurements of static pressure, impact pressure, and chemical composition were made at several positions within the burning zones of two simulated ramjet combustion chambers. From these measurements a complete mapping of compositions, velocity components, densities, and static pressures could be carried out. By calculation of the appropriate derivatives of the latter quantities, the differential form of the equation of continuity for the species desired could be solved for net reaction rate as a function of position, turbulent diffusion being neglected. By a similar technique the equation of momentum was used to obtain eddy viscosities. The latter results were used to estimate the effect of turbulent diffusion by assuming a turbulent Schmidt number of unity.It is concluded that the method of attack used is a reasonable approach to the problem of turbulent flame propagation, having a special advantage in that it can be used to discover relationships between the rate of reaction and the patterns of the mean flow.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 2 (1956), S. 55-58 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The physical processes are discussed by which a fluid is displaced from a porous medium during steady state viscous flow by another fluid of the same density and viscosity under conditions of complete miscibility of the two fluids. The displacement occurs on a microscopic scale as a result of combined convective and diffusional mixing. The length of the zone of mixing which comprises the displacement front is predicted to be dependent upon the rate of flow, the diffusion coefficient for the two-fluid system, the characteristics of the pore geometry, and the distance the front has traversed at the time of its observation.Experimental data are presented for the displacement of benzene by ethyl n-butyrate at several rates of flow from packed sand columns. These data show that the length of the frontal mixing zone after a prescribed distance of flow is greater at the higher rates of flow. The postulated dependence of the length of the front upon the diffusion coefficient and the pore geometry has not yet been investigated.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 28 (1982), S. 765-772 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A generalized mathematical model is developed to describe the process of multicomponent adsorption on activated carbon in fixed beds. Numerical, finite difference, solutions for the adsorption of binary, and ternary organic mixtures are shown to satisfactorily match previously published experimental data.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 598-604 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In 1954, G. I. Taylor derived an expression for an apparent axial dispersion coefficient for mass transfer in turbulent flow under the assumption of no mass transport between the tube wall and the fluid inside the tube. Taylor's expression has been verified in a number of experimental efforts for both mass and heat transfer.This work extends the results of Taylor to the case where there is a significant transport of heat from the tube wall to the fluid in the tube, such as in a double-pipe heat exchanger. Using an analysis similar to Taylor's, it is shown that the apparent axial dispersion coefficient is about one order of magnitude larger when a large radial gradient is present. Experimental data on a double-pipe heat exchanger show significantly improved correspondence with a dispersion-based model of the system when the larger dispersion coefficients are used.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 11 (1965), S. 770-955 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 24 (1982), S. 281-292 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Emulsan is a polymeric extracellular emulsifying agent produced by Acinetobacter RAG-1. Hydrocarbon-in-water emulsions (Vf of hydrocarbon of 0.01-0.10) were stabilized by small quantities of emulsan (0.02-0.2 mg/mL). Although both aliphatic and aromatic hydrocarbon emulsions were stabilized by emulsan, mixtures containing both aliphatics and aromatics were better substrates for emulsan than the individual hydrocarbon by themselves. The emulsan remained tightly bound to the hydrocarbon even after centrifugation as determined by (a) residual emulsan in the aqueous phase and (b) the fact that the resulting “cream” readily dispersed in water to reform stable emulsions. With hexadecane-to-emulsan weight ratio of 39 and 155, the noncoalescing oil droplets had average droplet diameters of 2.0 and 4.0 μm, respectively. Dialysis studies showed that the water-soluble dye Rhodamine B adsorbed tightly to the interface of hexadecane-emulsan droplets although the dye did not bind to either hexadecane or emulsan alone. At saturating concentrations of dye, 2.2 μmol of dye were bound per mg emulsan.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Proteins: Structure, Function, and Genetics 2 (1987), S. 273-282 
    ISSN: 0887-3585
    Keywords: protein-DNA interactions ; hydroxylamine mutagenesis ; dimerization ; protein structure-function ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine
    Notes: EcoRI endonuclease mutants were isolated in a methylase-deficient background following in vitro hydroxylamine mutagenesis of plasmid pKG2 (Kuhn et al.: Gene 44:253-263, 1986). Mutants which survived high-level endonuclease expression (IPTG induction) were termed null mutants. Sixtytwo of 121 null mutants tested by Western blot contained normal levels of endonuclease cross-reacting protein. The complete endonuclease gene was scquenced for 27 null mutants. This group was found to consist of 20 signle base-change missense mutations, 6 double mutations, and 1 triple mutation. Ten of the 20 signle mutations were clustered between residues 139 and 144. When examined with respect to the structure of the EcoRI-DNA complex (McClarin et al.: Science 234:1526-1541, 1986), these alterations werre found to fall predominantly into two classes: substitutions at the protein-DNA interface or substitutions at the protein-protein (dimer) interface. Protein from several of the mutants was purified and sized by using HPLC. Wild-type EcoRI endonuclease and protein from three of the DNA interface mutations (A1a139→Thr, Gly140→Ser, Arg203→Gln) appeared to be dimeric, while protein from subunit interface mutations (Glu144→Lys, Glu152→Lys, Gly210→Arg) migrated as monomers.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Chirality 2 (1990), S. 275-279 
    ISSN: 0899-0042
    Keywords: nucleotide analogue ; antiviral ; chiral separation ; complexation ; ion-pairing ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An acylonucleotide analogue, 1-[3-hydroxy-2-(phosphonyl-methoxy)propyl]cytosine (HPMPC), has shown activity against herpes simplex Type I and Type II viruses. An HPLC separation of the R- and S-enantiomers of HPMPC by ligand exchange using a mobile phase containing phenylalanine as the chiral modifier and copper(II) as the metal ion is reported.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 177 (1929), S. 137-144 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 182 (1929), S. 74-92 
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Während die Brom-Austreibung in Gegenwart von Sulfaten in allen Konzentrationen des betreffenden Salzes, je nach dem an- gewandten Sulfat, entweder beschleunigt oder verzögert wird, wirken alle Chloride niederer Konzentration ausschließlich verzögernd. Überall hat man ein Maximum der Verzögerung im Gebiet von etwa n/1-Endkonzentration. Es ergibt sich folgende Reihe ab- nehmender Verzögerung: \documentclass{article}\pagestyle{empty}\begin{document}$$ Me^I Cl 〉 Me^{II} Cl_2 \ge Me^{III} Cl_3. $$\end{document}Eine spezifische Kationenwirkung ist nicht feststellbar. HCl ver- hält sich genau wie ein neutrales Chlorid. Das H-Ion liegt in seiner Wirkung zwischen den ein- und mehrwertigen Kationen.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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