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  • Chemistry  (26)
  • Collusion  (2)
  • Polyethylene glycol  (2)
  • 1
    ISSN: 1432-2048
    Keywords: Abscisic acid ; Somatic embryogenesis ; Gene expression ; Heat shock protein ; Picea ; Polyethylene glycol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Three cDNAs (PgEMB22, 27 and 29) predicted to encode low-molecular-weight (LMW) heat-shock proteins (HSPs) were cloned and characterized from white spruce [Picea glauca (Moench) Voss] somatic embryo tissues by differentially screening a cotyledonary embryo cDNA library. Clone PgEMB22 is predicted to encode a putative mitochondria-localized LMW HSP, and PgEMB27 and 29 are predicted to encode different cytoplasmic class II LMW HSPs, although they share 84.7% identity within DNA coding regions and 83.0% identity for predicted proteins. They are developmentally regulated during somatic embryo development and subsequent embryo germination, in addition they show strong response to heat-shock stress. Transcripts of the two kinds of hsp genes could be detected in embryogenic tissues before induction of embryo maturation, but subsequently increased, being most abundant at late embryo stages. Gene expression levels were very low or not detectable in germinated plantlets or needle tissues from older plants. Abscisic acid and polyethylene glycol, stimulators for spruce embryo maturation, could also induce the hsp genes.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-2048
    Keywords: Abscisic acid ; Embryo abundant gene ; Gene expression ; Polyethylene glycol ; Picea ; Somatic embryogenesis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Embryogenic tissues of white spruce [Picea glauca (Moench) Voss] remain in an early developmental stage while cultured on 2,4-dichlorophenoxyacetic acid and N6-benzyladenine, but develop to cotyledonary embryos when these phytohormones are replaced by abscisic acid. Twenty-eight cDNAs were isolated from cotyledonary embryos by differential screening against immature embryo and non-embryonic tissues. Temporal expression patterns of these cDNAs during ABA-stimulated somatic embryo development were observed. This showed that clones could be allocated to various groups, including embryo-abundant, embryo-maturation-induced, and those whose expression was modulated during embryo development, germination or in non-embryogenic tissues. Expression corresponding to these cDNA clones showed that there were various responses to exogenous ABA or polyethylene glycol during a period of 48 h. Analyses of DNA and predicted amino acid sequence revealed that 12 of 28 cDNA clones had no known homologues, while others were predicted to encode different late-embryogenesis-abundant proteins, early methionine-labelled proteins, storage proteins, heat-shock proteins, glycine-rich cell wall protein, metallothionein-like protein and some other metabolic enzymes.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Review of industrial organization 9 (1994), S. 823-838 
    ISSN: 1573-7160
    Keywords: Collusion ; conjectures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Notes: Abstract A perennial topic in industrial economics is collusion. Kwoka and Ravenscraft (1986) developed a model to measure the collusiveness of conjectures across industries as a function of intra-industry rivalry among leading firms. But extensive literature suggests that the degree of collusion may also depend upon underlying market characteristics. We modify the Kwoka and Ravenscraft model to account for this. Our results suggest that underlying market characteristics do matter. Intra-industry rivalry and conjectures vary with the level and stability of concentration, and to a lesser degree with product homogeneity.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Heteroatom Chemistry 3 (1992), S. 189-192 
    ISSN: 1042-7163
    Keywords: Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Trifluoromethylthiocopper, a versatile reagent for the introduction of the trifluoromethylthio group into organic compounds, has been prepared in a crystalline form. The thiyl radicals, generated in situ from this precursor, cause the cleavage of the 3—S bond of di- and trisulfides to give unsymmetrical di- and trisulfides. Unsymmeirical n-butyl trifluoromethyl disulfide is formed by the cleaveage of the C—S bond of n-butyl sulfide.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 1527-1534 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Measures of mixing for laminar flow are developed from basic principles of continuum mechanics for infinitesimal rates of stretch. The entire analysis is performed from the basis of the eigenvalues and principal directions of the appropriate flow tensors. Measuring the rate of line growth, where the line marks the interface between two miscible fluids, in terms of the major eigenvalue provides a direct measure of the maximum rate of mixing. Two efficiency measures for mixing are derived in terms of the eigenvalues and their directions. The creation efficiency of the magnitude of the major eigenvalue as a function of the energy input into the flow field is evaluated. The orientation of the interface to the principal direction qualifies the mixing efficiency in laminar flow. The new theory is used to analyze two-dimensional and three-dimensional channels. The results demonstrate not only the continuum measures for mixing but also extend our present understanding on mixing and provide future directions.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 33 (1993), S. 1270-1278 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow in a three-dimensional channel with a sinusoidally-wavy, vertical wall is examined for the case of applied down- and cross-channel velocity components. An important parameter for the analysis of the nature of laminar mixing in the flow field occurs when the changes in the downstream direction can be decoupled from the changes in the cross-channel direction, thereby allowing for a two-dimensional solution of the system of equations. This paper shows the effect on the nature of laminar mixing when the decoupling of the momentum equations from a fully three-dimensional case to one where a two-dimensional solution can be performed. Experiments are performed on a channel with sinusoidally varying vertical walls that cover the range of decoupling criteria. Silicone pigmented either white or black was run in the apparatus, cured, and cross-sectioned. The cross sections embody a local, detailed history of the state of mixing as it proceeds down the mixer. The amount of mixing is presented as a function of position at each cross section for the different channel configurations. The nature of mixing changes from a linear growth rate in the amount of interfacial area to an exponential rate as the amplitude of the wave is increased. Results demonstrate the existence of chaos, islands, and the factors affecting the mixing behavior.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1874-1883 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this work, the bimodal/film model is compared with the cell model based on a case study using polystyrene/styrene devolatilization. It shows improvements over the cell model: (1) it requires a lower initial number of bubbles, which is more physically realistic and (2) it takes into account the observation of a limiting foam volume growth for a specific polymer in devolatilization. A stripper dispersion experiment was designed to investigate the effect of dispersed nitrogen stripper bubbles on the foam dynamics and devolatilization efficiency. The variables examined include polymer viscosity, initial volatile concentration, and the initial number and size of dispersed stripper bubbles. Polymer viscosity was the dominant factor in limiting the maximum foam volume expansion. The number and size of dispersed stripper bubbles show positive and negative effects (which are only secondary) on the maximum foam volume expansion, respectively. The initial volatile concentration has no effect on limiting the maximum foam volume expansion.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1861-1873 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Volatile species are removed from polymers by devolatilization. Foaming experiments using corn syrup and low-density polyethylene were carried out to investigate effects of volatile content, operating vacuum level and stripping agent in devolatilization. When foaming and rupture occur, a limiting foam volume growth was observed for a polymer regardless of the volatile content and the addition of stripper bubbles. A mathematical model was also developed to study the effect of stripper bubbles in polymer devolatilization. Based on the cell model for bubble growth, a bimodal model for foam growth is developed as the first step to describe the initial formation and growth of the volatile and stripper bubbles in polymer during devolatilization. When foaming and breakup occur at a critical foam volume expansion, a film model for mass transfer is used to model the second step of devolatilization. A numerical factorial study shows that the devolatilization section should be designed and operated to provide the screw channel sufficient free volume and residence time for the desired foam expansion.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 649-659 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Drop breakup mechanisms inside a cavity flow are presented for two immiscible fluids. Due to the nonuniform flow condition of the cavity, the breakup mechanism varied along the streamlines. The streamlines were characterized by stream zones A and B, where zone A possessed a methodical transient breakup governed by Tomotika's breakup via capillary instabilities, and the breakup mechanism of stream zone B consisted of tip streaming breakup, an inefficient breakup mechanism. The flow behavior near flight region had a significant role in the drop breakup mechanisms. The study of the evolution of drop dispersion showed that the matrix viscosity is critical in controlling the transient breakup process and that the shear rate increase had little or no effect on the drop breakup.
    Additional Material: 27 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Review of industrial organization 9 (1994), S. 379-392 
    ISSN: 1573-7160
    Keywords: Collusion ; efficiency
    Source: Springer Online Journal Archives 1860-2000
    Topics: Economics
    Notes: Abstract Through the 1970s and 1980s, the U.S. portland cement industry experienced a significant increase in average plant size and market concentration. A simultaneous equation model is developed to examine the effects of plant size and concentration on costs, prices and margins in that industry. The results indicate the presence of significant scale economies, but also show that prices and margins are increasing in concentration. Further analysis shows that almost one third of the cost savings associated with larger plants are passed on to producers through higher margins resulting from concomitant increases in concentration, rather than to consumers as lower prices.
    Type of Medium: Electronic Resource
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