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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 380-381 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 2198-2211 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In roll coating as in other coating processes the coating liquid often suffers changes in properties on the time of the coating flow, that is, from fractions of a second upward depending on the amount of recirculation and recycling. The agents of change may be chemical reaction, colloidal aggregation, or evaporation. Hence the mean residence time and the residence time distribution of the liquid are important to designers and operators of coating processes. Here, building on the examination of roll-coating systems by Benjamin et al. (1995), the residence times of liquid coated by representative arrays of multiple rolls in the “forward roll” mode and relatively starved feed condition (neglecting the possibly significant effects of “rolling banks” and other internal recirculations when they are present) are analyzed. The dynamic response of these transfer coaters to step changes in the feed gap and to periodic gap changes, as from roll and bearing run-out, are also analyzed. No reports of operating or laboratory experiments are available for comparison. Nevertheless the results make plain how these quality-limiting features may depend don the number of rolls used; their sizes, speed, and arrangement, and the properties of the coating liquid.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 587-597 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Blade coating is the most common method of coating paper, and it is applied in coating magnetic suspensions and adhesives. Typically, the blade's upstream edge is clamped into a rigid holder so that the blade and substrate form a converging wedge. The translating substrate drags liquid into the wedge, where liquid forces develop and deflect the elastic blade, but it is loaded externally to counteract the deflection. Liquid dragged past the blade and thus the coating thickness depend on the elastohydrodynamic interaction among blade, liquid, and loading. Shell theory and lubrication flow theory describe the interaction by means of differential equations that are shown to be equivalent to Saita and Scriven's (1985) earlier formulation but that lead to a computationally more efficient analysis. Predictions computed agree with those of the earlier formulation and with experiments. Moreover, the new predictions illustrate effects of normal force loading and broaden the theory of blade coating.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 41 (1995), S. 1045-1060 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Roll coaters for applying liquid coating to continuous strip or web are, with some two-roll exceptions, systems of three or more rolls in which liquid passes through two or more gaps or nips between rolls. Yet most of the literature on roll coating is devoted to some of the 11 distinct flows in individual gaps or nips. This article analyzes how the final coated layer thickness in several types of forward roll transfer and reverse roll coating systems depends, at steady state, on the number of rolls, their speeds, the gaps between roll pairs, and the doctoring of recycle films from the rolls. The inputs to the analysis are elementary mass balances at the gaps, and simple gap performance equations that approximate well the available experimental and theoretical findings about flow rates and film-splits at individual gaps. The results are fundamentals-based means of understanding, comparing, predicting, and ultimately designing performance of multiple roll systems.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 42 (1996), S. 55-67 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The competition between drying and reactions in a liquid coating containing precursors to a random network polymer can give rise to a variety of drying phenomena. Solidification, or gelation, of the polymer may occur before, after, or during the removal of solvents from the coating. Rates of drying and reaction are probed by solving the equations of mass transfer by diffusion along with chemical reaction in one dimension. Solutions to this system of equations are obtained by Galerkin's method with finite-element basis functions and entail large-scale computation. Skinning, or solidification at the surface of the coating while the bulk is still liquid, occurs in thick coatings when the diffusional resistance to drying is significant, that is, at high mass-transfer coefficients. Homogeneous solidification occurs in thin coatings at low mass-transfer coefficients. Drying regime maps represent these solidification phenomena as regions in parameter space.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 560-568 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This article shows the settling behaviors of flocculated, magnetic and nonmagnetic iron oxide suspensions. It is unique, since in the literature on settling of model submicron flocculated particulate suspensions there is no direct visualization of the structures and how they change during settling. Channeling, cracking, and a novel collapse phenomenon were detected during settling. Causes were investigated using lapse videorecording for side and top views. The effect of air bubbles was shown to contribute to the accelerated settling of the suspension by creating channels that conduct oil to the settling front. Settling heights were recorded for long periods of time (up to a year) for iron oxide suspensions of different concentrations. Decreasing tube diameters delayed settling, and magnetic interparticle forces produced smaller final settling heights. The effect of magnetic forces was interpreted in terms of a floc model. The model finds magnetic flocs 1.3 to 1.4 times denser than their nonmagnetic analogs. Finally, a mechanism is put forth to interpret the settling behavior observed.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 161-174 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The flow in the metering gap of a reverse roll coater is examined by experiments and finite element solutions of the Navier-Stokes equations. At high speed ratios and capillary numbers, the metered film flow deviates strongly from predictions of lubrication theory: the wetting line moves through the gap center and the metered film thickness passes through a minimum. The two flow instabilities found are ribbing, a sinusoidal cross-web waviness extending smoothly down-web; and cascade, an irregular V-shaped cross-web wave, repeated quasiperiodically down-web. Experimental operability diagrams define parameter ranges where these instabilities and the steady two-dimensional flow are encountered. Ribbing behavior is understood by consideration of the pressure gradient at the free surface. The mechanism of cascade is the intrusion through the gap of the wetting line, which causes the metered film to thicken and eventually reattach to the metering roll in a cyclical manner.
    Additional Material: 21 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 7 (1961), S. 524-526 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 12 (1966), S. 1151-1157 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The collocation method and a maximum principle are used to generate pointwise, improvable upper and lower bounds for solutions of the transport equation. This new method of analysis is applicable to the unsteady state transport equation with a specified velocity field as well as to other problems which have a maximum principle. An application to unsteady state transfer to a fluid in ideal stagnation flow illustrates the method.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 24 (1978), S. 1010-1014 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Formulas obtained by approximation of the rigorous expression for the interfacial tension of multicomponent, polyatomic fluids are shown to provide accurate and simple estimates of the composition dependence of the surface tension of nonaqueous, binary solutions at low vapor pressures. Similar formulas are recommended for multicomponent (that is, more than two components) solutions.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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