ISSN:
1434-4475
Keywords:
Azo Dyes
;
Diamino-alkoxy-pyridine-carbonitriles
;
UV-VIS spectra
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The isomeric 4,6-diamino-2-alkoxy- (3), and 2,4-diamino-6-alkoxy-3-pyridine-carbonitriles (4) are obtained by treatment of 2-amino-1,1,3-tricyanopropene (1) with sodium alkoxides. Separation is based on their differentpK a -values (3 a=2.01,4 a=4.17). Coupling reaction of3 a-c with benzenediazonium chloride in strong acidic medium leads to the yellow azo dyes5 a-c, whereas coupling of4 a requires a buffered solution (pH 4–6) to yield6. The UV-VIS spectra of the isomer pyridines and the azo dyes are discussed.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00799957
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