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Conductometric studies of DyCl3 in dilute aqueous solution (1993)

Fourest, B. ; Bury, R. ; Morss, L. R. ; [et al.]

Springer

Journal of solution chemistry 22 (1993), S. 151-162

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ISSN: 1572-8927

Keywords: Conductivity ; Dy3+ion ; electrolyte mixtures ; hydrolysis

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The limiting conductivity of Dy3+(aq) has been determined for the first time by linear extrapolation of conductivity measured in dilute aqueous solutions of (DyCl3+HCl) at 25°C as λo(Dy3+, aq) = (62.9±0.7) S-cm2-eq-1. A second set of conductivity measurements in dilute aqueous solutions of DyCl3 has given evidence of very slight hydrolysis of the cation, with a first hydrolysis constant of 6 x 10−8 mol-dm−3 (pK=7.2±0.5) calculated by applying the Onsager-Kim law of electrolyte mixtures.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00650681

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