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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Oxidation of metals 51 (1999), S. 317-331 
    ISSN: 1573-4889
    Keywords: OXIDATION ; γ-TiAl INTERMETALLIC ; ELECTRODEPOSITEDNi-La2O3 ; COMPOSITE FILM
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A coating of nickel withLa2O3 particles waselectrodeposited on the surface of γ-TiAl toimprove its high-temperature oxidation resistance. Theexperimental results showed that contrary to theoxidation of bare specimens, the electrodepositedNi-La2O3 composite-coated onesexhibited much better resistance to both isothermal andcyclic oxidation in air at 1000 and 900°C. For theoxidation of the Ni-La2O3 composite-coated γ-TiAl EPMA/EDX microanalyses revealed that after the composite film had beenthoroughly oxidized, a La2O3-richNiO layer close to the gas-scale interface and twoalumina-rich layers, with one beneath the NiO layer and the otheradjacent to the γ-TiAl matrix, were produced inthe scale. The results indicated that the preferentiallyformed La2O3-doped NiO layerretarded the growth of rutile and favored the formation of twoalumina-rich layers. The mechanism of the effect of theelectrodeposited Ni-La2O3composite on the oxidation behavior of γ-TiAl isdiscussed in detail.
    Type of Medium: Electronic Resource
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