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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 205-212 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In this paper the synthesis and properties of resacetophenone oxime-formaldehyde resin are described. The number-average molecular weights of the resin determined by vapor-pressure osmometry and nonaqueous conductometric titration are 2200 ± 10% and 2500 g/mol, respectively. Cu(II), Ni(II), and Co(II) chelates of the resin were prepared. Elemental analysis of the chelates indicates a metal to ligand ratio of 1:2. The diffuse reflectance spectra and magnetic moments of Ni(II) and Co(II) chelates show tetrahedral structure, whereas Cu(II) chelate shows a square planar structure. Infrared spectral studies show that the metals are coordinated through the nitrogen of the oximino group and oxygen of the phenolic group. The presence of methylene bridges is also indicated by IR spectral studies. The thermal behavior of the resin and its metal chelates are also discussed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 6 (1986), S. 129-153 
    ISSN: 0271-2091
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A comparative study of eight discretization schemes for the equations describing convection-diffusion transport phenomena is presented. The (differencing) schemes considered are the conventional central, upwind and hybrid difference schemes,1,2 together with the quadratic upstream,3,4 quadratic upstream extended4 and quadratic upstream extended revised difference4 schemes. Also tested are the so called locally exact difference scheme5 and the power difference scheme.6 In multi-dimensional problems errors arise from ‘false diffusion’ and function approximations. It is asserted that false diffusion is essentially a multi-dimensional source of error. Hence errors associated with false diffusion may be investigated only via two- and three-dimensional problems. The above schemes have been tested for both one- and two-dimensional flows with sources, to distinguish between ‘discretization’ errors and ‘false diffusion’ errors.7 The one-dimensional study is reported in Reference 7. For 2D flows, the quadratic upstream difference schemes are shown to be superior in accuracy to the others at all Peclet numbers, for the test cases considered. The stability of the schemes and their CPU time requirements are also discussed.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 20 (1995), S. 1179-1197 
    ISSN: 0271-2091
    Keywords: adaptive grids ; equidistribution ; compressible viscous aerodynamics ; CFD modelling ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A technique is described for the adaptation of a structured control volume mesh during the iterative solution process of the Navier-Stokes equations. The scalar equidistribution method is adopted, in conjunction with a Laplace-like grid solver to make a curvilinear body-fitted grid sensitive to local flow gradients. Hence, whilst the total number of grid nodes remains constant during a computation, their relative position is continuously adjusted to promote clustering of cells in regions where gradients are high. The focus of this work is in compressible aerodynamics, where such clustering would be desirable in regions containing shocks but also in boundary layers. The technique is three-dimensional and operates in a series of user-defined grid subdomains or patches. These patches act as reference frames within which grid activity takes place. Bi-cubic splines are extensively used to define the aerodynamic surfaces forming the calculation boundaries and to ensure that grid movement does not compromise surface integrity. The technique is applied to aerofoils, wing surfaces, transonic ducts and nozzles and a supersonic wedge cascade. Significant sharpening of both normal and oblique shock discontinuities is demonstrated over static grid simulations and with fewer overall grid nodes. The technique is successful in both inviscid and viscous (turbulent) simulations.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 5 (1985), S. 225-244 
    ISSN: 0271-2091
    Keywords: Convection-Diffusion ; Differencing Schemes ; Discretization Errors ; False Diffusion ; Upwind Scheme ; Higher Order Schemes ; Accuracy ; Stability ; Computational Cost ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A comparative study of seven discretization schemes for the equations describing convection-diffusion transport phenomena is presented. The (differencing) schemes considered are the conventional central- and upwind-difference schemes, together with the Leonard,1 Leonard upwind1 and Leonard super upwind difference1 schemes. Also tested are the so called locally exact difference scheme2 and the quadratic-upstream difference scheme.3,4 In multidimensional problems errors arise from ‘false-diffusion’ and function approximations. It is asserted that false diffusion is essentially a multidimensional source of error. No mesh constraints are associated with errors in function approximation and discretization. Hence errors associated with discretization only may be investigated via one-dimensional problems. Thus, although the above schemes have been tested for one- and two-dimensional flows with sources, only the former are presented here. For 1D flows, the Leonard super upwind difference scheme and the locally exact scheme are shown to be far superior in accuracy to the others at all Peclet numbers and for most source distributions, for the test cases considered. Furthermore, the latter is shown to be considerably cheaper in computational terms than the former. The stability of the schemes and their CPU time requirements are also discussed.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 20 (1982), S. 1985-1992 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermally stable and semiconducting poly-Schiff bases are synthesized by condensing 4,4′-diacetyl diphenyl ether with o-, m-, and p-phenylene diamines, benzidine, and ethylene diamine under different experimental conditions. These bases are insoluble in common organic solvents. They are characterized by infrared (IR) and viscosity measurements, thermal analysis, and the study of electricel properties at various temperatures. Variation of electrical conductivity σ with temperature followed the empirical relation σ = σ0e-E*/kT.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 21 (1983), S. 3027-3032 
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Free-radical copolymerization of methyl acrylate (MA) with N-p-chlorophenylmaleimide (NPCMI) and N-p-bromophenylmaleimide (NPBMI) initiated by AIBN in cyclohexanone solution at 75°C was studied. The copolymer composition has been determined from the nitrogen content and NMR spectra of the copolymers. The reactivity ratios have been calculated by ML, FR, KT, and JJ methods. Q and e values of NPCMI and NPBMI have also been calculated by the Alfrey-Price Q-e scheme.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 26 (1988), S. 2279-2304 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An important limiting factor in the accurate modelling of fluid flow problems is the numerical representation of the convection terms in the Navier-Stokes equations. This paper reviews several approaches used to approximate the convection terms and reduce the so-called false-diffusion errors, within the context of finite-difference and finite-volume methods. Numerical errors are characterized as those due to discretization of the differential terms and those due to the influence of the multidimensional nature of the flow. Necessary criteria are identified which a numerical scheme must satisfy, if it is to be a candidate, at least in terms of accuracy and practicality, for the successful solution of the Navier-Stokes equations. One of the criteria is the need of the scheme to account explicitly for the multidimensionality of the flow in the transport of scalar variables. All schemes except Raithby's SKEW approximation are deficient in this respect. However, the SKEW scheme does not satisfy some of the other criteria and does not always perform well. A new scheme called CUPID (Corner UPwInDing), which is based on the ideas of the SKEW scheme, yet obeys more of the criteria identified above, is described. The scheme is tested on a series of discriminating test problems which, the authors contend, demonstrate its potential for practical use in solving accurately the Navier-Stokes equations.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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