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  • 1
    Electronic Resource
    Electronic Resource
    Temperature effect in separation of fullerene by high-performance liquid chromatography (1994)
    Springer
    Chromatographia 39 (1994), S. 453-459 
    Details
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Fullerenes ; Octadecylsilicas ; Temperature effect
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The effect of column temperature, especially at low temperatures, on the separation of fullerenes on monomeric and polymeric octadecyl silica (ODS) bonded phases has been studied. Decreasing the column temperature induces an increase in selectivity. The best temperature for the separation of fullerenes was determined for both types of ODS phase with n-hexane eluent. The selectivity for higher fullerenes on monomeric phases becomes similar to that on polymeric phases to low temperature. It has been found that as the carbon content of monomeric phases is increased, the selectivity also becomes similar to polymeric phases.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02278762
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Retention of fullerenes by octadecyl silica. Correlation with NMR spectra at low temperatures (1995)
    Springer
    Chromatographia 40 (1995), S. 507-512 
    Details
    ISSN: 1612-1112
    Keywords: Column liquid chromatography ; Fullerenes ; Retention vs NMR spectra ; C18 phases ; Low temperature separations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The temperature effect on the retention of fullerenes in the range 80°C to −70°C in liquid chromatography (LC) has been examined using octadecylsilica stationary phases (ODS). It has been found that the maximum retention temperature lies around −10°C with a highly carbon loaded ODS phase. Solid state CPMAS NMR measurements on the stationary phases indicated that the relaxation time at the 30 ppm methylene signal changes with the temperature and has a minimum relaxation time at the temperature which closely matches the maximum retention temperature observed in chromatography. The interpretation of both NMR spectroscopic and LC chromatographic data are discussed.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF02290260
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    Cluster cations ejected from liquid metal ion source: alkali metals (Li, Na) and group IV elements (Si, Ge, Sn, Pb) (1989)
    Springer
    The European physical journal 12 (1989), S. 225-227 
    Details
    ISSN: 1434-6079
    Keywords: 36.40 ; 79.70 ; 35.20.X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Cluster abundance of Li n + (n≤19), Na n + (n≤25), Si n z+ (n≤8 forz=1, 3≤n≤7 forz=2), Ge n z+ (n≤11 forz=1, 3≤n≤9 forz=2,n=4 forz=3), Sn n z+ (n≤7 forz=1, 3≤n≤9 forz=2,n=4 forz=3) and Pb n z+ (n≤6 forz=1, 5≤n≤7 forz=2) ejected from a liquid metal ion source has been investigated by mass spectrometry. The abundance spectra of alkali metal clusters showed distinct maxima and steps atn=3, 7, 9, 13 and 19 for Li, and atn=3, 5, 11, 13 and 19 for Na. Mass spectra of Si, Ge and Sn clusters were very similar each other, showing intensity drops aftern=4 and 6 (and alson=10 for Ge) for singly charged clusters. The magic numbers observed are discussed in terms of stability of charged clusters.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01426943
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  • 4
    Electronic Resource
    Electronic Resource
    Abundance of Na cluster ions ejected from a liquid metal ion source (1989)
    Springer
    The European physical journal 11 (1989), S. 87-91 
    Details
    ISSN: 1434-6079
    Keywords: 36.40 ; 79.70 ; 35.20.X
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Sodium cluster ions Na+ n withn ranging up to 25 have been observed from a liquid sodium ion source by using a magnetic mass analyzer. Ion intensity as a function of cluster size showed distinct steps and local maxima atn=3, 5, 11, 13 and 19 (magic numbers), and a pronounced odd-even alternation. The features in the ion abundance curve are attributed to the relative stability of cluster ions. The observed magic numbers are only partially explained by the electronic shell model, indicating need to include a consideration of atomic structure in a cluster.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01436588
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    Paper (German National Licenses)
    Fulltext
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