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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 14 (1992), S. 763-766 
    ISSN: 0392-6737
    Schlagwort(e): Glass transitions ; Calorimetry
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary We report here first observations of the decrease in heat capacity during isothermal vitrification of a thermosetting polymer. A new experimental method has been developed for this study which allows simultaneous measurements of both the heat capacity and the enthalpy released as chemical reactions occur in quasi-isothermal conditions. During the curing the heat capacity of a thermoset first increases slightly, undergoes an abrupt decrease in a narrow range of time and thereafter slowly decreases. The abrupt decrease represents the irreversible transition of the liquid to a vitreous solid which is equivalent to the reversible glass transition appearing in a supercooled liquid when the temperature is lowered.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Il nuovo cimento della Società Italiana di Fisica 18 (1996), S. 1443-1448 
    ISSN: 0392-6737
    Schlagwort(e): Glass transitions ; Calorimetry ; Dielectric loss and relaxation
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Summary A method and an instrument has been developed for measuring almost simultaneously and continuously in time three different quantities: i) the heat evolved during the course of exothermic reactions, ii) the heat capacity and iii) the dielectric spectra of a liquid or solid sample. By using this instrument, we have studied the decrease in the d.c. conductivity and the increase in the relaxation time as molecules in an isothermally kept liquid chemically react to produce, irreversibly, a macromolecular structure until the liquid vitrifies and becomes rigid. The number of covalent bonds formed in the structure,n, has been calculated and the dielectric relaxation time, τ, is related ton. This τ increases progressively more rapidly withn, and decreases, of course, on increasing the temperature. A compensation between these two effects determines the dynamic behaviour observed during rate heating. The effect of temperature is found to predominate. Such observations have been made possible by means of the new instrument.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 31 (1993), S. 265-271 
    ISSN: 0887-6266
    Schlagwort(e): Nylon-12 ; dielectric properties ; crystallization ; calorimetry ; Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The dielectric properties of 30% crystalline dry Nylon-12 have been measured over the frequency range 10-105 Hz and temperature range 300-450 K, and the effect of its annealing at 423 K investigated both by dielectric measurement and differential scanning calorimetry. Annealing causes its crystallization to α phase, which increase the dc conductivity and decreases the contribution to orientation polarization, but does not alter the shape of the relaxation spectrum. The orientation polarization in Nylon-12 involves two processes, each of which occurs above the glass-transition temperature of Nylon-12, but only the spectra of the lowest temperature process could be clearly resolved. © 1993 John Wiley & Sons, Inc.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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