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  • 1
    ISSN: 1435-1536
    Keywords: Critical coagulation concentration ; iron (III) hydroxide sol ; silver iodide sol ; sedimentation ; Hamaker constant
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A method for determining the critical coagulation concentration (C c) from the change in the transmittance of the sol with stand time after adding a coagulating agent is discussed. Potassium nitrate was used as the coagulating agent because the specific adsorption of electrolyte ions on the particle and the hydrolysis of electrolyte ions are negligible. Apparent critical coagulation concentrations,C c a, of iron (III) hydroxide and silver iodide sols were obtained from the transmittance vs. potassium nitrate concentration curves for various stand times. The values ofC c a decreased with increasing stand time. TheC c a value obtained for the shortest stand time was closer toC c obtained from the initial turbidity change of the sol by applying Rayleigh's law. The Hamaker constant for the particle in water was calculated from theC c a value obtained at the shortest time and the experimentally determined outer Helmholtz plane potential. The calculated Hamaker constants were comparable to the theoretical values for iron (III) hydroxide and silver iodide.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Colloid & polymer science 267 (1989), S. 434-439 
    ISSN: 1435-1536
    Keywords: Nylon particle ; adhesion ; removal ; electrokinetic potential ; Hamaker constant ; heterocoagulation ; electrostatic ; van der Waals interactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The effect of surface properties of particles on their adhesion and removal was investigated using an immersed system consisting of nylon particles and a quartz plate. The nylon particles were dyed with a reactive dye in order to change their properties and were used for the adhesion and removal experiments in comparison with undyed particles. The electrokinetic potentials of the particles were measured by micro-electrophoresis and the Hamaker constants were independently evaluated using experimental values of dispersive component of surface free energy determined by the Wilhelmy technique. The experimental results were used for the discussion of particle adhesion and removal on the basis of the heterocoagulation theory. The differences in adhesion and removal efficiencies between dyed and undyed particles were explained in terms of the electrostatic and dispersive van der Waals interaction by considering the differences in thier properties, the electrokinetic potential and the Hamaker constant, due to dyeing.
    Type of Medium: Electronic Resource
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