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  • 1
    Electronic Resource
    Electronic Resource
    The identification of some water-soluble arsenic species in the marine brown algae Fucus distichus (1997)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 11 (1997), S. 931-940 
    Details
    ISSN: 0268-2605
    Keywords: arsenic ; arsenosugars ; Fucus distichus ; high-performance liquid chromatography (HPLC) ; inductively coupled plasma mass spectrometry (ICP MS) ; HPLC-ICP MS ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The extraction and clean-up procedures developed to isolate the water-soluble arsenic species present in the marine macroalga Fucus distichus, from British Columbia, Canada, are described. The arsenic species were extracted into methanol and then subjected to gel-permeation and ion-exchange chromatography. Fractions high in arsenic were identified by using graphite furnace atomic absorption spectroscopy (GF-AAS), and further investigated by using high-performance liquid chromatography coupled to inductively coupled plasma-mass spectrometry (HPLC-ICP MS). By using different HPLC columns and mobile-phase conditions, the four major arsenic-containing compounds present in the macroalga were positively identified as arsenosugars; one minor compound remained unidentified. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 2
    Electronic Resource
    Electronic Resource
    The characterization of arsenosugars in commercially available algal products including a Nostoc species of terrestrial origin (1997)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 11 (1997), S. 797-803 
    Details
    ISSN: 0268-2605
    Keywords: arsenic ; speciation ; algae ; arsenosugar ; high-performance liquid chromatography (HPLC) ; inductively coupled plasma-mass spectrometry (ICP-MS) ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The arsenic species present in a range of commercially available dried-algal food products were characterized by HPLC-ICP-MS. The products of marine origin contain up to four dimethylarsinylribosides (1) in the 8-49 ppm range and some also contain dimethylarsinic acid (DMAA). These species are easily extracted and account for most of the arsenic burden. One sample of a freshwater alga Nostoc sp. was found to contain a lower concentration of arsenic, 3 ppm, and only 34% of this was extractable. The extract representing 1 ppm of arsenic contained one of the arsenosugars 1 found in the marine samples (93%), the rest being DMAA. This is the first report of the identification of an arsenosugar from an organism of terrestrial origin. The implications of this result in connection with the global arsenic cycle are discussed. © 1997 John Wiley & Sons, Ltd.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 3
    Electronic Resource
    Electronic Resource
    Seasonal changes in arsenic speciation in Fucus species (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 243-251 
    Details
    ISSN: 0268-2605
    Keywords: arsenic ; speciation ; algae ; Fucus gardneri ; arsenosugar ; high-performance liquid chromatography (HPLC) ; inductively coupled plasma-mass spectrometry (ICP-MS) ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Arsenic speciation in a brown alga, Fucus gardneri, collected in Vancouver, B.C., Canada, was carried out by using high-performance liquid chromatography-inductively coupled plasma-mass spectrometry (HPLC-ICP-MS). Hydride generation-atomic absorption spectrometry (HG-AAS) was used for total arsenic determination. The relative amounts of some arsenosugars 1 in growing tips are found to be different in comparison with the remainder of the plant. Fucus samples collected in summer contain 9 ppm of total arsenic. Most of the arsenic species are extractable. Fucus samples collected in winter contain relatively higher amounts of arsenic, 16-22 ppm, but only low amounts of this are extractable. © 1998 John Wiley & Sons, Ltd.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
  • 4
    Electronic Resource
    Electronic Resource
    The production of methylated organoantimony compounds by Scopulariopsis brevicaulis (1998)
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 12 (1998), S. 827-842 
    Details
    ISSN: 0268-2605
    Keywords: Scopulariopsis brevicaulis ; hydride generation ; antimony ; biomethylation ; biotransformation ; solid-phase extraction ; sudden infant death syndrome (SIDS) ; volatile antimony ; Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Cultures of the fungus Scopulariopsis brevicaulis were grown in antimony-rich media. Although volatile compounds of other elements were readily detected in the culture headspace, volatile antimony compounds were formed irreproducibly and at only ultratrace levels. In order to monitor the media for nonvolatile methylantimony compounds, a method of sample preparation was developed, based on solid-phase extraction. This enabled the separation of large quantities of soluble inorganic antimony species from trace amounts of organoantimony compounds before speciation by HG-GC-AAS. By this methodology methylated antimony compounds were detected at concentrations of 0.8- 7.1 µg Sbl-1 in all media in which S. brevicaulis was grown in the presence of antimony(III) compounds. These methylantimony species were not detected in any of the nonliving or medium-only controls. Methylated compounds were not detected where S. brevicaulis was grown in the presence of antimony(V) compounds. This is the first study to show that antimony(III) compounds are biomethylated by S. brevicaulis under aerobic-only growth conditions. Copyright © 1998 John Wiley & Sons, Ltd.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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    Paper (German National Licenses)
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