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  • Inorganic Chemistry  (4)
  • 25.70.Lm  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Dynamics and thermalization in violent collisions between40Ar and Ag at 27 MeV/nucleon (1991)
    Springer
    The European physical journal 340 (1991), S. 63-77 
    Details
    ISSN: 1434-601X
    Keywords: 25.70.Gh ; 25.70.Jj ; 25.70.Lm
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract For the violent collisions of 27 MeV/nucleon40Ar with Ag, coincidence measurements have been made between heavy residues and intermediate mass fragments (3≦Z≦14) or light charged particles. From the analysis of the correlation between heavy residues (mass and velocity) and intermediate mass fragments, the main characteristics of the dominant mechanisms, fusion and partially damped collisions preceded or accompanied by a preequilibrium emission, are presented. Balances concerning mean values of parallel linear momentum, mass and atomic number, are established and confirm that a complete description of violent collisions was obtained. Then thermalization is discussed, first in terms of excitation energies derived from kinematics between heavy residues and intermediate mass fragments, and secondly in terms of initial temperature estimates derived from light charged particle spectra. Very hot nuclei (T⋍5.7–6.6 MeV) are produced over a large impact parameter range from very central collisions to medium peripheral ones. Various experimental results are compared to predictions obtained with semi-classical calculations (Landau-Vlasov equation). From their good agreement one may conclude that, depending on the impact parameter, thermal equilibrium is achieved within 4–10×10−22 s.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01284482
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  • 2
    Electronic Resource
    Electronic Resource
    Incomplete deep-inelastic scattering in20Ne+197Au collisions at 20 MeV/nucleon (1988)
    Springer
    The European physical journal 330 (1988), S. 303-310 
    Details
    ISSN: 1434-601X
    Keywords: 25.70.Lm ; 25.70.Np
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Correlations between emission angles and energies of coincidentα-particle projectile-fragment pairs have been measured for the20Ne+197Au system at 390 MeV beam energy. Theα-particles observed close to the direction of the projectile-like fragment were found to result essentially from sequential projectile decay. Starting from the close-geometry data, the contribution of sequentially emittedα-particles was calculated by Monte Carlo simulations for the entire angular range. For deep inelastic events, the measured angular correlations exhibit a spectacular excess over the calculated correlation. This excess is centred close to the beam direction but on the opposite side of it with respect to the detected projectile-like fragment. The correspondingα-particles have velocities around 85% of the projectile velocity indicating emission in an early reaction phase.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01294874
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  • 3
    Electronic Resource
    Electronic Resource
    Projectile break-up with two outgoing intermediate-mass fragments in 26 AMeV32S+197Au (1993)
    Springer
    The European physical journal 345 (1993), S. 29-35 
    Details
    ISSN: 1434-601X
    Keywords: 25.70.Lm ; Mn
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Correlations between two intermediate-mass fragments resulting from 840 MeV32S projectiles interacting with197Au were measured. The angular correlations and absolute two-fragment cross sections agree with predictions of a semi-microscopic model for direct dynamic projectile break-up. This suggests a predominantly direct mechanism for the production of intermediate-mass fragment pairs. It is argued that the intensity of such a channel which, compared to decays yieldingα particles, is much larger than observed for the sequential decay of corresponding primary excited nuclei, supports the direct-break-up interpretation. The model mechanism yields also strongly damped projectile fragments of intermediate mass.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01290336
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  • 4
    Electronic Resource
    Electronic Resource
    Über Metallcarbonyle. XXXIX. Aminsubstituierte Rheniumcarbonyle (1941)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 248 (1941), S. 269-275 
    Details
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Kohlenoxydverbindungen des Rheniums, die Halogenopentacarbonyle wie das reine dimere Pentacarbonyl, erweisen sich der CO-Substitution durch Pyridin oder o-Phenanthrolin zugänglich, wie dies schon früher bei den Metallen der Eisen- und Chromgruppe aufgedeckt wurde. Die aminsubstituierten Rheniumcarbonyle enthalten sämtlich noch wenigstens 3 Mol CO pro Rheniumatom, d.h.es werden stets nur 2Mol CO durch 2Mol Pyridin oder 1 Mol o-Phenanthrolin ersetzt: ReHal(CO)3Pyr2 nnd ReHal(CO)3 Phthrl sowie Re(CO)3Pyr2 und Re(CO)3, Phthrl2; letztere sind eventuell dimer wie das Rheniumpentacarbonyl. Die aminsubstituierten Rheniumcarbonyle erinnern bezüglich ihrer Entstehungsweise, ihres Baus und ihrer großen Beständigkeit durchaus an die aminsubstituierten Carbonyle der Chromgruppe.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19412480305
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  • 5
    Electronic Resource
    Electronic Resource
    Über Metallcarbonyle. XXXVIII. Über Rheniumpentacarbonyl (1941)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 248 (1941), S. 256-268 
    Details
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Nachdem die Bemühungen, durch Hochdrucksynthese aus metallischem Rhenium oder durch weitere Reaktionen der Halogenopentacarbonyle reines Rheniumcarbonyl zu erhalten, unter verschiedensten Bedingungen erfolglos blieben, wurde gefunden, daß oxydische Rheniumverbindungen, insbesondere Re2O7 oder auch ReO4K u. a. unter höherem CO-Druck und bei höherer Temperatur direkt halogenfreies, reines Rheniumcarbonyl liefern. Über den Reaktionsmechanismus der einfach zu formulierenden Umsetzungen werden verschiedene Vorstellungen entwickelt.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19412480304
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  • 6
    Electronic Resource
    Electronic Resource
    Über Metallcarbonyle. XXXVII. Über Rhenium-halogeno-pentacarbonyle, ihre Bildungstendenz und Eigenschaften (1941)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 248 (1941), S. 243-255 
    Details
    ISSN: 0863-1786
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Im Anschluß an die Auffindung der Halogenopentacarbonyle des Rheniums Re(CO)5Halg, über die früher berichtet wurde, wird das Bildungsbestreben dieser Verbindungen genauer untersucht. Es zeigt sich, daß sie bereits unter wesentlich milderen Bedingungen aus Rheniumhalogeniden entstehen, und zwar nimmt die Bildungstendenz in der Reihe Chlorid → Bromid → Jodid zu. Letzteres erhält man bereits im Kohlenoxydstrom bei gewöhnlichem Druck aus ReJ6K2, für Bromid und Chlorid, aus Komplexen oder normalen Rheniumhalogeniden, empfiehlt sich die Anwendung eines geringen Überdrucks von 10 bzw. 30 at Kohlenoxyd. Insgesamt ist für die Entstehung der Halogenopentacarbonyle weniger die Höhe des CO-Drucks als die Temperatur (200-230°) maßgebend.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19412480303
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  • 7
    Electronic Resource
    Electronic Resource
    Zur Darstellung des Natriumbromits und bromitfreier HypobromitlösungenVorbericht: Z. anorg. allg. Chem. 363, 321. (1968) (1970)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 372 (1970), S. 127-133 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Sodium bromite may be prepared by dismutation of hypobromite solution produced by the addition of bromine to concentrated caustic soda at 0 °C, the hypobromite being destroyed after the maximum bromite concentration has been reached. Using bromine water or bromine vapour diluted by nitrogen at low temperatures, it is possible to prepare bromite-free hypobromite solutions.
    Notes: Eine aus Brom und Natronlauge hergestellte Natriumhypobromitlösung wird zur Darstellung des Natriumbromits durch Disproportionierung benutzt. Das im Maximum der Bromitkonzentration vorhandene Hypobromit muß zerstört werden.Mit Bromwasser oder stickstoffverdünnten Bromdämpfen kann bei niedrigen Temperaturen eine bromitfreie Hypobromitlösung hergestellt werden.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19703720204
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