ISSN:
0009-2940
Keywords:
Key Words: Transition-metal ions / Bond activation, CH and CC / Tandem mass spectrometry / Amines, aliphatic
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The mechanisms of the deceptively similar gas-phase chemistry of amine complexes RC(CH3)2CH2NH2/M+ (R = H, CH3 M = Fe, Co, Ni) are uncovered by the use of deuterium-labeled compounds. It is demonstrated that the details of CH/CC bond-activation reactions are strongly metal-ion-dependent, as is the product distribution itself.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19901230446
Permalink