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  • 1
    ISSN: 0044-2313
    Keywords: Pentacarbonyl(diorganostibine)chromium, -molybdenum, -tungsten complexes ; Tetracarbonyl(diorganostibine)chromium and -molybdenum complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Tetra- and Pentacarbonyl Compounds of Chromium, Molybdenum and Tungsten with Oxygen- and Sulfurbridged Distibines and with Chlorodiphenylstibine as Complex LigandsThe penta- and tetracarbonyl complexes of chromium, molybdenum and tungsten with the stibines Ph2SbCl and (Ph2Sb)2X (X = O and S) are obtained by photochemical reaction of the hexacarbonyls in thf and by thermic ligand substitution of (η4-C7H8)M(CO)4 (M = Cr, Mo) with stibines.In the case of (Ph2Sb)2X monodentate or bidentate coordination is possible.
    Notes: Die Synthese von Penta- und Tetracarbonylen der Metalle der 6. Nebengruppe mit Antimonliganden des Typs Ph2SbCl und (Ph2Sb)2X (X = O und S) erfolgt durch photochemische Umsetzung der Metallhexacarbonyle in THF bzw. durch thermische Ligandsubstitution aus (η4-C7H8)M(CO)4 (M = Cr, Mo) mit den Antimonliganden.Bei Verwendung der Chelatstibane (Ph2Sb)2X läßt sich sowohl eine monodentate als auch eine bidentate Koordination verwirklichen.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 619 (1993), S. 2061-2065 
    ISSN: 0044-2313
    Keywords: Dicarbonylbis(triphenylphosphite)(stibine)iron complexes ; Bis[dicarbonylbis(triphenylphosphite)iron](stibine) complexes ; Dicarbonyl(η5-methylcyclopentadienyl)(stibine)manganese complexes ; Bis[dicarbonyl(η5-methylcyclopentadienyl)manganese](stibine) complexes ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Complexes of Iron and Manganese with Oxygen-, Sulfur-, and Methylene-bridged Distibines and with Chlorodiphenylstibine as LigandsThe photochemical reaction of CO3Fe[P(OPh)3]2 and of MeCpMn(CO)3 with the stibines Ph2SbCl and (Ph2Sb)2X (X = O, S and CH2) yields mononuclear complexes (CO)2[P(OPh)3]2FeL and °Cp(CO)2MnL (L = Ph2SbCl, (Ph2Sb)2X) and the stibine bridged binuclear complexes °CO)2[P(OPh)3]2Fe{(Ph2Sb)2X}Fe(CO)2[P(OPh)3]2 and °Cp(CO)2Mn{(Ph2Sb)2X}Mn(CO)2MeCp.
    Notes: Durch photochemische Umsetzung von (CO)3Fe[P(OPh)3]2 und von MeCpMn(CO)3 mit Anti-monliganden des Typs Ph2SbCl und (Ph2Sb)2X (X = O, S und CH2) können Einkernverbindungen (CO)2[P(OPh)3]2FeL und MeCp(CO)2MnL (L = Ph2SbCl, (Ph2Sb)2X sowie die über Distibanliganden verbrückten Zweikernverbindungen (CO)2[P(OPh)3]2Fe{(Ph2Sb)2X}Fe(CO)2[P(OPh)3]2 und MeCp(CO)2Mn{(Ph2Sb)2X}Mn(CO)2MeCp synthetisiert werden.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
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