ISSN:
0570-0833
Keywords:
Ion-pair solvation complexes
;
Solvation complexes
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
In solvents of low polarity, salts containing a carbanion, e.g. fluorenylsodium, or a radical anion, e.g. coronenesodium, can exist as contact ion pairs or as solvent separated ion pairs. Particular interest attaches to the complexes of ion pairs with the strongly solvating, polydentate polyglycol dimethyl ethers (glymes) and with crown compounds. These systems can be studied by optical spectroscopy, NMR spectroscopy, and other methods.
Additional Material:
15 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.197201121
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