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Catalyzed Addition of Aldehydes to Activated Double Bonds - A New Synthetic Approach (1976)

Stetter, Hermann

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 15 (1976), S. 639-647

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ISSN: 0570-0833

Keywords: Addition ; Aldehydes ; Synthetic methods ; Esters ; Ketones ; Nitriles ; Chemistry ; General Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: In the presence of cyanide ions as catalyst, aromatic and heterocyclic aldehydes can be smoothly added to α,β-unsaturated ketones, esters, and nitriles in aprotic solvents to form γ-diketones, 4-oxo carboxylic esters, and 4-oxo nitriles. Thiazolium salts in the presence of bases are also suitable catalysts; they permit not only addition of aromatic and heterocyclic aldehydes but also the addition of aliphatic aldehydes.

Additional Material: 9 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/anie.197606391

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