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  • Polymer and Materials Science  (2)
  • M3+-substituted vanadyl phosphates  (1)
  • historical seismology  (1)
  • 1
    ISSN: 1572-8943
    Schlagwort(e): 1-butene isomerization ; M3+-substituted vanadyl phosphates ; structural characterization ; thermal characterization ; vanadyl phosphate
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract A set of new materials with general formula [M(H2O)]X(VO)1−XPO4·2H2O (M 3+=Al, Cr, Ga, Mn), isomorphous with layered tetragonal VOPO4·2H2O and having potential catalytic properties, have been characterized by TG and DTA, X-ray diffraction and surface acid strength. During heating the compounds transform in the monohydrated and anhydrous phases, all maintaining a layered structure, with a proper interlayer spacing. Catalytic tests performed with 1-butene show that theM 3+-vanadyl phosphates greatly improve the conversion of the olefine with respect to pure vanadyl phosphate.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Natural hazards 22 (2000), S. 225-268 
    ISSN: 1573-0840
    Schlagwort(e): Italy ; central Apennines ; active fault ; paleoseismology ; historical seismology ; seismic hazard
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Energietechnik , Geographie , Geologie und Paläontologie
    Notizen: Abstract Quaternary tectonics and paleoseismologicalinvestigations have defined a reliable framework ofactive faults in the southern Umbria and AbruzziApennines. Two sets of NW–SE to NNW–SSE trending, 16to 33 km-long, normal and normal-oblique faults orfault systems have caused the displacement of LatePleistocene–Holocene deposits and landforms within theinvestigated sector. Available data on verticaloffsets indicate that both Late Pleistocene–Holoceneand Quaternary (since the later part of the EarlyPleistocene; 0.9–1 Ma) slip rates range between 0.4and 1.2 mm/yr (range 0.6–0.8 mm/yr preferred).Paleoseismological investigations show that recurrenceintervals for surface faulting events are alwaysgreater than 1,000 years and are usually greater than2,000 years. Both paleoseismological data andlong-term seismicity show that activation of theinvestigated faults may result in earthquakes ofM = 6.5–7.0. The extension rate across the two sets ofprimary faults ranges between 0.7 and 1.6 mm/yr.Horizontal seismic strain has been calculated to be0.5–0.6 mm/yr, based on the summation of the seismicmoment of M 〉 5.3 earthquakes which have affected theinvestigated area since 1200 AD. This value may belower than that inferred through geological data,probably because the seismological record reliable forthe addition of the seismic moments covers a too shorttime window (about 800 years) to be consideredrepresentative of the tectonic activity in theinvestigated area. This conclusion iscorroborated by the large recurrence intervalper fault (〉1,000–2,000 years) inferred frompaleoseismological analysis. A comparison of theactive-fault framework and historical-seismicitydistribution indicates that the entire eastern set ofactive faults has likely not been activated since 1000AD, thus indicating that the elapsed time since thelast activation for several faults of the investigatedarea may be greater than 1,000 years. In terms ofhazard, the highest probability of activation isrelated to the eastern set faults, due to theobservation that the elapsed time for some of thesefaults may be similar to the recurrence interval. Asan example, paleoseismological andarchaeoseismological data indicate that the elapsedtime for the Mt. Vettore and Mt. Morrone Faults may begreater than 1,650 and 1,850 years, respectively.These data may have significant implications for riskrelated to a number of towns in central Italy and tothe city of Rome. As for the latter, in fact,monumental heritage has suffered significant damagedue to earthquakes of M 〉 6.5 which originated in theinvestigated Apennine sector.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 94 (1981), S. 63-89 
    ISSN: 0003-3146
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Es wird ein historischer Überblick der Entwicklung von Ziegler-Natta-Katalysatoren für die Propylenpolymerisation gegeben. Nach dem jahrelangen Einsatz von Titantrichlorid wurden in den 70er Jahren neue Katalysatoren der sogenannten zweiten Generation eingeführt, die schneller wirken und zu kristallineren Produkten führen. Ausführlich wird auf die neuere Entwicklung zu Katalysatoren der „dritten Generation“, speziell auf ihre morphologischen Eigenschaften eingegangen. Diese Katalysatoren ergeben sehr hohe Ausbeuten, sterisch sehr regelmäßige Polymeren und eröffnen Möglichkeiten zur Vereinfachung der Polypropylentechnologie und Energieeinsparung. In Zukunft wird die Polypropylenherstellung nur aus der eigentlichen Polymerisationsstufe bestehen, und es wird keinerlei Nachbehandlung wie Zentrifugieren oder Extrudieren erforderlich sein.
    Notizen: A historical survey about the development of Ziegler-Natta catalysts for polymerization of propylene is given. After having employed catalysts based on titaniumtrichloride for several years, in the 70's catalysts of the so-called second generation were introduced, which are more effective and yield products of higher crystallinity. Catalysts of the so-called third generation and their morphological properties are extensively dealt with. These catalysts give high yields and highly stereoregular polymers and enable simplification of polypropylene technology and energy saving. In the future polypropylene manufacturing will probably consist only of the polymerization steps with no need for centrifuging, extruding or another post-treatment.
    Zusätzliches Material: 16 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Weinheim : Wiley-Blackwell
    Acta Polymerica 39 (1988), S. 81-90 
    ISSN: 0323-7648
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Beschreibung / Inhaltsverzeichnis: Neue Katalysatorsysteme für die Synthese von Polypropylen und Propylencopolymeren wurden entwickelt. Der Wachstumsmechanismus der morphologischen Strukturen der Polymere und einige Besonderheiten des Prozesses werden beschrieben. Einige Eigenschaften der erhaltenen Polymere und Copolymere werden vorgestellt, und die Vorteile und zukünftigen Entwicklungen dieser Technologie werden diskutiert.
    Notizen: New catalyst systems for the synthesis of polypropylene and polypropylene copolymers have been developed. The growth mechanisms of morphological structure of the polymers and some features of the process are described. Some properties of the obtained homopolymers and copolymers are presented, and the advantages and future developments of the process technology are discussed.
    Zusätzliches Material: 22 Ill.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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