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  • NEXAFS  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 62 (1996), S. 417-427 
    ISSN: 1432-0630
    Keywords: PACS: 75.70Ak; 75.30Gw; 73.20 ; r
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Abstract.  Nickel allows to study the largest variety of phenomena in the magnetism of UHV ultrathin films. The low critical temperature of ≈630 K for the bulk favors experiments from 0 K to above T c and from one monolayer to infinite thick films. The thickness dependence of T c (d) for the (001) and the (111) orientation is compared. Susceptibility measurements in UHV are presented, and from χmax the film geometry can be deduced. Ferromagnetic resonance measures the second- and fourth-order anisotropy constants. These give a clear understanding of when and how the reorientation transition from the in-plane to the perpendicular orientation occurs and its nature. Magnetic resonance and circular X-ray dichroism measure the spin and orbital parts of the magnetic moment μ, its anisotropy Δμ, and the 3d and 4sp contributions. Finally, we show how a 4 Monolayer (ML) Ni (001) film can be transformed into NiO by controlled oxygen dosage and thermal treatment.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Topics in catalysis 10 (2000), S. 199-207 
    ISSN: 1572-9028
    Keywords: chemisorption ; molecular dynamics ; SEXAFS ; NEXAFS
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract A useful and necessary step to understand the complexity of catalysis is to first study the simple prototype systems which involve elements active in such reactions. Studies throwing light on gas–metal interaction are of vital importance. The X-ray absorption spectroscopy can provide vital information for catalysis as one probes the system on a very local scale. We present state of the art surface EXAFS measurements of carbon, nitrogen and oxygen adsorbed on well characterised metal surfaces (Ni and Cu). The present contribution highlights from experimental measurements supported by improved theoretical calculations that temperature and angular dependent studies are essential for a reliable structural analysis and to gain an insight into absorbate–substrate bonding and kinetics. The low Z metal systems were found suitable to detect unambiguously the photoelectron backscattering by interstitial charge densities.
    Type of Medium: Electronic Resource
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