ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Experimental data obtained from the study of the behaviour of monoalkyl phosphates ROP(O)(OH)O- or monoalkyl phosphonates C6H5P(O)(OR)O- in aquo-alcoholic (H2O + R′OH) solutions suggest: (1) in the case of monoalkyl phosphonates the exchange of R and R′ must proceed by a direct alcoholysis; (2) in the case of monoalkyl phosphates, where the scission of the ester at about pH 4,5 proceeds via the intermediate formation of metaphosphate ion PO3-, R′OPO3H- can also be formed by the addition of R′OH to PO3- (competitive to the addition of water) besides direct alcoholysis of ROPO3H-.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19690520849
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