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  • PACS. 33.15.Kr Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility - 34.70.+e Charge transfer - 61.48.+c Fullerenes and fullerene-related materials  (1)
  • PACS: 36.40.-c Atomic and molecular clusters – 32.10.Dk Electric and magnetic moments, polarizability – 31.15.Ew Density functional theory  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Static electric dipole polarizabilities of alkali clusters (1999)
    Springer
    The European physical journal 9 (1999), S. 243-248 
    Details
    ISSN: 1434-6079
    Keywords: PACS: 36.40.-c Atomic and molecular clusters – 32.10.Dk Electric and magnetic moments, polarizability – 31.15.Ew Density functional theory
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract. We have measured the static dipole polarizability of lithium and sodium clusters (n=1-22). Values measured for sodium are in agreement with previous experiments. While the polarizability per atom for sodium clusters decreases slowly as a function of the cluster size, a sharp decrease between sizes 1 and 4 is observed for lithium clusters. Experimental values are compared to Density Functional Theory (DFT/PW91) calculations. The size evolutions for sodium and lithium cluster polarizabilities are well reproduced by our calculations. The sharp decrease observed for small lithium clusters is discussed in terms of electronic density.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s100530050433
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Electric dipole moment and charge transfer in alkali-C molecules (2000)
    Springer
    The European physical journal 12 (2000), S. 147-151 
    Details
    ISSN: 1434-6079
    Keywords: PACS. 33.15.Kr Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility - 34.70.+e Charge transfer - 61.48.+c Fullerenes and fullerene-related materials
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: We have measured the electric dipole moment of isolated alkali-C60 molecules (with alkali = Li, Na, K, Rb, and Cs) by molecular beam deflection experiments. The dipole increases from 12.4 D for LiC60 to 21.5 D for CsC60. These results are compared to those deduced from an analytical polarizable-ion model. This comparison shows that there is a strong electron transfer from the alkali atom to the C60 cage, which is almost complete for KC60 and RbC60.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s100530070051
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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