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Digitale Medien

Electric dipole moment and charge transfer in alkali-C molecules (2000)

Antoine, R. ; Rayane, D. ; Benichou, E. ; [weitere]

Springer

The European physical journal 12 (2000), S. 147-151

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ISSN: 1434-6079

Schlagwort(e): PACS. 33.15.Kr Electric and magnetic moments (and derivatives), polarizability, and magnetic susceptibility - 34.70.+e Charge transfer - 61.48.+c Fullerenes and fullerene-related materials

Quelle: Springer Online Journal Archives 1860-2000

Thema: Physik

Notizen: Abstract: We have measured the electric dipole moment of isolated alkali-C60 molecules (with alkali = Li, Na, K, Rb, and Cs) by molecular beam deflection experiments. The dipole increases from 12.4 D for LiC60 to 21.5 D for CsC60. These results are compared to those deduced from an analytical polarizable-ion model. This comparison shows that there is a strong electron transfer from the alkali atom to the C60 cage, which is almost complete for KC60 and RbC60.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/s100530070051

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