Library

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • 1995-1999  (3)
  • Physical Chemistry  (3)
Source
Material
Years
Year
Keywords
  • 1
    Electronic Resource
    Electronic Resource
    Kinetics of the reaction of O(3P) with CF3NO (1995)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 27 (1995), S. 369-377 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A laser flash photolysis-resonance fluorescence technique has been employed to study the kinetics of the reaction of O(3P) with CF3NO (k2) as a function of temperature. Our results are described by the Arrhenius expression k2(T) = (4.54 ± 0.70) × 10-12 exp[(-560± 46)/T] cm3molecule-1 s-1 (243 K ≤ T ≤ 424 K); errors are 2σ and represent precision only. The O(3P) + CF3NO reaction is sufficiently rapid that CF3NO cannot be employed as a selective quencher for O2(a1Δg) in laboratory systems where O(3P) and O2(a1Δg) coexist, and where O(3P) kinetics are being investigated. © 1995 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550270408
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Branching ratios for BrO production from reactions of O(1D) with HBr, CF3Br, CH3Br, CF2ClBr, and CF2HBr (1998)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 30 (1998), S. 555-563 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Laser-flash photolysis of RBr/O3/SF6/He mixtures at 248 nm has been coupled with BrO detection by time-resolved UV absorption spectroscopy to measure BrO product yields from O(1D) reactions with HBr, CF3Br, CH3Br, CF2ClBr, and CF2HBr at 298±3 K. The measured yields are: HBr, 0.20±0.04; CF3Br, 0.49±0.07; CH3Br, 0.44±0.05; CF2ClBr, 0.31±0.06; and CF2HBr, 0.39±0.07 (uncertainties are 2σ and include estimates of both random and systematic errors). The results are discussed in light of other available information or O(1D)+RBr reactions. © 1998 John Wiley & Sons, Inc. Int J Chem Kinet 30: 555-563, 1998
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
  • 3
    Electronic Resource
    Electronic Resource
    Kinetics of the reactions of atomic chlorine with H2S, D2S, CH3SH, and CD3SD (1995)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 27 (1995), S. 359-368 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Time-resolved resonance fluorescence detection of atomic chlorine following 266-nm laser flash photolysis of Cl2CO/RSR'/N2 mixtures has been employed to study the kinetics of Cl reactions with H2S(k1), CH3SH(k2), D2S(k3), and CD3SD(k4) as a function of temperature (193-431 K) and pressure (25-600 torr). Arrhenius expressions which describe our results are (units are 10-11 cm3molecule-1s-1; uncertainties are 2σ, precision only) k1 = (3.69 ± 0.33) exp[(208 ± 24)/T], k2 = (11.9 ± 1.7) exp[(151 ± 38)/T], and k3 = (1.93 ± 0.32) exp[(168 ± 42)/T]. The Cl + CD3SD reaction has been studied at 299 K and 396 K; values for k4 at these two temperatures are essentially the same as those measured for k2. Our results are compared with earlier studies and the mechanistic implications of observed negative activation energies and H—D kinetic isotope effects are discussed. © 1995 John Wiley & Sons, Inc.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550270407
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...