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Digitale Medien

Poly(P-phenylene sulfide) hexafluoroarsenate: A novel conducting polymer (1982)

Clarke, T. C. ; Kanazawa, K. K. ; Lee, V. Y. ; [weitere]

New York : Wiley-Blackwell

Journal of Polymer Science: Polymer Physics Edition 20 (1982), S. 117-130

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Details

ISSN: 0098-1273

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie , Physik

Notizen: Poly(p-phenylene sulfide) (PPS) is a melt- and solution-processible polymer which on treatment with AsF5 forms a blue-black material with a conductivity of 1-10 Ω-1 cm-1. Thermopower measurements indicate that the resulting polymer is p type, consistent with partial oxidation of the PPS by the AsF5. The rate and extent of this doping process prove to be particularly sensitive to the degree of crystallinity of the starting polymer. There is also evidence of crosslinking of the polymer chains during the reaction with AsF5. The details of both the chemistry and physics of the doping of PPS and several of its derivatives are presented.

Zusätzliches Material: 7 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1982.180200110

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