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Kinetics of polypeptide denaturationPaper presented at the 9th Annual Meeting of the Biophysical Society, San Francisco, March 1965. (1965)

McQuarrie, D. A. ; McTague, J. P. ; Reiss, H.

New York : Wiley-Blackwell

Biopolymers 3 (1965), S. 657-663

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ISSN: 0006-3525

Schlagwort(e): Chemistry ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: The irreversible kinetics of polypeptide denaturation and renaturation is discussed in terms of the Zimm-Bragg equilibrium model. An exact solution is presented for situations in which the back reaction is negligible. The solution is given in terms of parameters which are rate constants for the elementary processes in denaturation or renaturation. The formalism is also applicable to reactions of linear polymers in which the reactivity of a given site depends on the state of reaction of its neighbors.

Zusätzliches Material: 4 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/bip.360030605

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Digitale Medien

Tailored heterogeneity indices in anionic polymerization (1966)

Eisenberg, A. ; McQuarrie, D. A.

New York : Wiley-Blackwell

Journal of Polymer Science Part A-1: Polymer Chemistry 4 (1966), S. 737-750

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ISSN: 0449-296X

Schlagwort(e): Physics ; Polymer and Materials Science

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Equations are derived for the differential molecular weight distribution curve and for the heterogeneity index for several types of delayed initiator addition in anionic polymerization. All the results are in closed and easily used form, and depend only upon the product of the rate constant of the propagation reaction, the total initiator concentration, and a parameter representative of the rate of initiator addition. The results are plotted versus the above-mentioned product, so that one can determine the heterogeneity index to be expected under a wide range of the variables involved.

Zusätzliches Material: 3 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/pol.1966.150040401

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