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  • Polymer and Materials Science  (3)
Source
Material
Years
Keywords
  • 1
    Electronic Resource
    Electronic Resource
    The formation of polymerizable tubules (1990)
    New York, NY : Wiley-Blackwell
    Polymers for Advanced Technologies 1 (1990), S. 27-32 
    Details
    ISSN: 1042-7147
    Keywords: Crystallization ; Phospholipids ; Diacetylene ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: We have been investigating the crystallization behavior of the phospholipid amphiphile, 1,2 bis (10, 12-tricosadiynol)-sn-glycero-3-phosphocholine, DC8,9PC, which forms both vesicles and hollow tubules as well as Langmuir Blodgett monolayers and multilayers. This material has polymerizable diacetylene groups in equivalent positions on the two hydrocarbon tails. The direct crystallization from solution of this amphiphile has been studied using different solvent mixtures and temperatures. The Langmuir Blodgett technique was also used to compress and orient the tubules.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pat.1990.220010105
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Epitaxial crystallization of polyesters on inorganic and organic substrates (1978)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 16 (1978), S. 895-906 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A series of low-molecular-weight linear polyesters were epitaxially crystallized from dilute solution and the melt on a variety of organic and inorganic substrates. The rod-like polyester crystals which were formed assumed general orientations in alignment with substrate geometry. This yielded monodirectional orientation of these crystals on one of the organic substrates, and bidirectional orientation on the other surfaces. Heterogeneous nucleation on the organic substrates, trioxane and naphthalene, induced the growth of much larger epitaxial crystals than have previously been observed on inorganic substrates. Those polyesters, with a high percentage of methylene units per chain repeat, crystallized in an unusual polymorphic form when in contact with the organic substrates. Polymorphic transformation to the normal form was not possible under thermal treatment or with increased crystal thickness. The expected relationship between dipolar alignment in the polymer crystal and this polymorphism was established.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1978.180160513
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    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Poly(bismethylene hydroquinone) (PBHQ). I. Synthesis and characterization (1985)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 23 (1985), S. 2659-2668 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Poly(bismethylene hydroquinone) (PBHQ) has been synthesized. Fourier transform infrared, 13C solid-state CP/MAS NMR and elemental analysis provide strong evidence of two methylene bridges per hydroquinone molecule. The polymer was (1) air oxidized using ammonia and (2) chemically oxidized using bromine/KOH. The initial structure and oxidation process was studied by comparison of the unoxidized and oxidized polymers using Fourier transform infrared, elemental analysis, and 13C solid-state CP/MAS NMR.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1985.170231008
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    Paper (German National Licenses)
    Fulltext
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