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  • 1
    Electronic Resource
    Electronic Resource
    Kinetic aspects of dyeing processes (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 2987-2996 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dyeing of textiles was classified into two main categories: reactive and adsorptive dyeing. A mathematical model for each case was developed on the basis of a pore model concept. The validity of the proposed models was confirmed by comparison with existing experimental data on dyeing of reactive dyes in cellulose and acid dyes in nylon. It was further desired that the proposed models be checked by experimental results in high fixation regimes. The overdyeing phenomenon may be simulated by intrafiber diffusion with simultaneous multimodal adsorption.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1982.070270822
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Dyeing process in a finite dyebath (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 4745-4752 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The processes of adsorptive and reactive dyeings of polymer film in a finite bath were formulated on the basis of pore model concept. The influence of the bath ratio on the fractional uptake or fixation was numerically analyzed. The time of half-dyeing is proportional to the bath ratio to the power of about 0.9 within the present computational conditions. This fact is in contrast to the finding that, in an infinite bath with the same dye concentration as the initial value in a finite bath, the time of half-dyeing is inversely proportional to the dye concentration. The relation of the total uptake or fixation to the dimensionless dyeing time θ multiplied by γ0.9 is independent of the bath ratio within an error of 5% or 8%.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1982.070271219
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  • 3
    Electronic Resource
    Electronic Resource
    Diffusion of dyes in adsorptive dyeing (1983)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 3817-3825 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The concentration dependence derived from both steady-state permeation and unsteady-state dyeing runs for a system of acid dye C. I. Acid Blue 182-nylon 6 film was analyzed in terms of parallel diffusion with simultaneous multimodal adsorption proposed in the previous paper. The present dyeing process was governed by the surface diffusion incorporating three kinds of Langmuirean adsorption modes. The concentration dependence of the diffusion coefficient of the cationic dye C. I. Basic Red 22 in the anionically modified polyester fiber Dilana measured by Ostrowska et al. [B. Ostrowska, A. Narebska, and H. Krzystek, J. Appl. Polym. Sci., 26, 463 (1981)] was satisfactorily interpreted by the parallel diffusion incorporating two kinds of Langmuirean adsorption modes.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1983.070281221
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  • 4
    Electronic Resource
    Electronic Resource
    Transport of acid dye in nylon and concentration dependence of the diffusion coefficient (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 305-315 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dyeing kinetics of an acid dye (C. I. Acid Blue 40) in a nylon 6 film were investigated using partition-cell and film-roll methods at 80°C and pHs 2.3 and 3.05. The concentration dependence of diffusion coefficient of the dye in the nylon substrate measured by both methods was interpreted in terms of parallel diffusion with biomodel sorption of the Nernst and Langmuir modes. As the concentration of dye increases, the transport of dye inside the nylon film becomes dominated by pore diffusion and surface diffusion of sorbed Nernst populations.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070330204
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  • 5
    Electronic Resource
    Electronic Resource
    Chemical engineering aspects of reactive dyeing (1985)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 30 (1985), S. 4113-4125 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The process of dyeing with reactive dyes was formulated on the basis of diffusion of dye species in the pores of polymer phase accompanied by fixation reaction with fiber substrate on the pore wall incorporating hydrolysis of dye species. The effect of the hydrolysis on the fractional fixation was numerically analyzed under various levels of bath ratio and degree of mixing in the dyebath. The simulation model was presented to yield the unlevelness arisen from lack of uniformity of degree of mixing in the dyebath.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1985.070301013
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    Paper (German National Licenses)
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  • 6
    Electronic Resource
    Electronic Resource
    Diffusion of an acid dye in nylon - in relation to sorption and diffusion of a gas in glassy polymers (1986)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 32 (1986), S. 5567-5574 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The steady-state permeation rate data of an acid dye in a nylon film were analyzed via dual-mode sorption and mobility model based on gradients of concentration. The model used incorporates diffusion in a porelike region, unlike diffusion of a gas in a glassy polymer. There was some possibilities of the Nernst to the Langmuir mode diffusion jump, and the diffusivity was estimated.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1986.070320624
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  • 7
    Electronic Resource
    Electronic Resource
    Diffusion of acid dyes in nylon film in the presence of inorganic salts (1984)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Chemistry Edition 22 (1984), S. 61-67 
    Details
    ISSN: 0360-6376
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The concentration-dependence measured by steady-state permeation and unsteady-state dyeing methods for a system of acid dye C.I.Acid Blue 182-nylon 6 film in the presence of inorganic salts such as NaCl, Na2SO4, and K2SO4, was analyzed in terms of parallel diffusion with simultaneous multimodal adsorption. It would found that the dyeing process with added NaCl was governed by surface diffusion with two kinds of Langmuir adsorption, whereas with added Na2SO4 and K2SO4 it was governed by surface diffusion with three kinds of Langmuir adsorption.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1984.170220106
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