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  • 1
    Electronic Resource
    Electronic Resource
    Kristall- und Molekülstruktur von Arsen-tris(trifluoracetat) (1996)
    Springer
    Monatshefte für Chemie 127 (1996), S. 1215-1220 
    Details
    ISSN: 1434-4475
    Keywords: Coordination of As(III) ; Structure ; Stereoisomeres
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary Arsenictris(trifluoroacetate) (1) crystallizes monoclinic in the space group Cc witha=1229.3,b=1697.9,c=1243.5 pm, β=110.01°, andZ=8. The trifluoroacetic acid ions acts as chelating ligands. Additionally they are bridging crystallographic independent molecules. As has a coordination number of 3+3(+2). The unit cell contains two sets of chirameres.
    Notes: Zusammenfassung Arsen-tris(trifluoracetat) (1) kristallisiert monoklin in der Raumgruppe Cc mita=1229.3,b=1697.9,c=1243.5 pm, β=110.01° undZ=8. Die Trifluoracetatanionen fungieren gegenüber As als zweizähnige Liganden und verknüpfen die beiden kristallographisch unabhängigen Moleküle zusätzlich intermolekular. As erreicht dadurch gegenüber O die Koordinationszahl 3+3(+2). Die Elementarzelle enthält zwei Sätze von chirameren Molekülen.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00807787
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  • 2
    Electronic Resource
    Electronic Resource
    Antimontribenzoat (1995)
    Springer
    Monatshefte für Chemie 126 (1995), S. 1045-1050 
    Details
    ISSN: 1434-4475
    Keywords: Coordination of Sb(III) ; Structure ; Enantiomers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary The Δ isomer of (C6H5CO2)3Sb crystallizes rhombohedrally (hexagonal axes) in the space group R3 witha=1944.0 pm,c=422.3 pm, andZ=3. The molecules are stacked parallel to 001; Sb has a coordination number of 3+3 (Sb-O: 208 and 256 pm, resp.).
    Notes: Zusammenfassung Das Δ-Isomer des Antimontribenzoats kristallisiert rhomboedrisch (hexagonale Aufstellung) in der Raumgruppe R3 mita=1944.0 pm,c=422.3 pm undZ=3. Die Moleküle sind parallel zu 001 gestapelt. Sb hat gegenüber O die Koordinationszahl 3+3 (Sb-O: 208 bzw. 256 pm).
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00811375
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  • 3
    Electronic Resource
    Electronic Resource
    Zur Struktur zweier Arsen- und Antimontricarboxylate (1996)
    Springer
    Monatshefte für Chemie 127 (1996), S. 461-468 
    Details
    ISSN: 1434-4475
    Keywords: Coordination of As(III) and Sb(III) ; Structure ; Enantiomers
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Summary Arsen-tris(2,2-dimethylpropionate) (1) crystallizes monoclinic in the space group P21/n witha=926.2,b=2158.6,c=983.7 pm, β=94.92°, andZ=4. As has a coordination number of 3+3. Antimony tripropionate (2) crystallizes monoclinic in the space group P21/c witha=930.2,b=863.0,c=1575.2 pm, β=90.27, andZ=4. The molecules are bridged to chains; therefore, Sb reaches the coordination number 3+3 (+3).
    Notes: Zusammenfassung Arsen-tris(2,2-dimethylpropionat) (1) kristallisiert monoklin in der Raumgruppe P21/n mita=926.2,b=2158.6,c=983.7 pm, β=94.92° undZ=4. As hat gegenüber O die Koordinationszahl 3+3. Antimontripropionat (2) kristallisiert monoklin in der Raumgruppe P21/c mita=930.2,b=863.0,c=1575.2 pm, β=90.27 undZ=4. Die Moleküle sind intermolekular zu Ketten verknüpft, wodurch Sb die Koordinationszahl 3+3 (+3) erreicht.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00807070
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  • 4
    Electronic Resource
    Electronic Resource
    Applicability of a continuum solvation model to the octanol water transfer: CFF91 based model for amino acids (1995)
    New York : Wiley-Blackwell
    Biopolymers 36 (1995), S. 599-605 
    Details
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A continuum hydration model based upon the atomic charges provided with the CFF91 force field [A. B. Schmidt and R. M. Fine (1994) Molecular Simulation, 13. 347-365] has been extended to the octanol-water transfer. The electrostatic component of the transfer free energy is calculated using the finite-difference solution to the Poisson-Boltzmann equation while the nonpolar contributions are assumed to be proportional to the solute-excluded volume in water. All atomic charges and radii besides the aromatic carbon radius are equal in both solvents. The octanol dielectric constant and the probe radius are the main fitting parameters defining the octanol phase. The model has been tested for 38 organic molecules related to the amino acid residues and generally provides a high accuracy. In particular, the mean unsigned error for N-acetyl amino acid amides is 0.5 kcal/mol. © 1995 John Wiley & Sons, Inc.
    Additional Material: 4 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bip.360360505
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  • 5
    Electronic Resource
    Electronic Resource
    Eine neue methode zur herstellung von hydroxyterminierten polydienen (1990)
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 174 (1990), S. 69-80 
    Details
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: It is shown, that hydroxyterminated polydienes of good microstructure and functionality and a narrow molecular weight distribution can be prepared using di-hydroxyethyl-azo-bis-isobutyramide as an initiator. The activation energy of the initiator decay has been determined by volumetric measurement of the nitrogen evolved in this reaction.
    Notes: Es wird gezeigt, daß hydroxyterminierte Polydiene mit guter Mikrostruktur und Funktionalität sowie enger Molekulargewichtsverteilung unter Verwendung von Azobis-isobuttersäure-di-hydroxyethylamid hergestellt werden können. Die Aktivierungsenergie des Initiatorzerfalls wurde durch volumetrische Messung des bei dieser Reaktion freiwerdenden Strickstoffs bestimmt.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/apmc.1990.051740106
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  • 6
    Electronic Resource
    Electronic Resource
    Graphit als Werkstoff im chemischen Apparatebau (1951)
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 2 (1951), S. 93-95 
    Details
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Allgemeine Eignung von Graphit als Apparatewerkstoff  -  Entwicklung von Graphitwärmeaustauschern durch die I. G. Farbenindustrie, Bitterfeld  -  Imprägniermittel und -verfahren zur Verringerung der Porosität des Graphits  -  Verbindung von Bauelementen aus Graphit.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/maco.19510020304
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  • 7
    Electronic Resource
    Electronic Resource
    Produktabtrennung bei Alkohol-Fermentationen (1992)
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 64 (1992), S. 871-872 
    Details
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/cite.3306409153
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  • 8
    Electronic Resource
    Electronic Resource
    Polymers and resins. Their chemistry and chemical engineering. Brage Golding. Van Nostrand, New York, 1959. 744 pp. $15.00. (1959)
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 40 (1959), S. 277-278 
    Details
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1959.1204013626
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  • 9
    Electronic Resource
    Electronic Resource
    Über die polymeranaloge verzweigung von amylose durch isocyanatzucker25. Mitt. der Reihe: Über natürliche und synthetische Amylose. 24. Mitt.: W. BURCHARD, Makromolekulare Chem. 64 (1963) 110. (1963)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 65 (1963), S. 114-121 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: By addition of 1-isocyanat-tetraacetylglucose to the hydroxylgroups of unsubstituted amylose we introduced branches are introduced in linear polysaccharides. The degree of branching attained was calculated from acetyl and nitrogen values. The highest degree of branching was about 0.8. The desacetylated branched polysaccharides were soluble in water.
    Notes: Mit Hilfe der Additionsreaktion von 1-Isocyanato-tetraacetylglucose an die Hydroxylgruppen von Polysacchariden wurden in unsubstituierte Amylose Glucoseverzweigungen eingeführt. Der Verzweigungsgrad konnte aus Stickstoff- und Acetylbestimmungen ermittelt werden. Es wurden Verzweigungsgrade von über Z = 0,8 erreicht. Die von den Acetylgruppen befreiten Substanzen waren z. T. gut wasserlöslich.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1963.020650116
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  • 10
    Electronic Resource
    Electronic Resource
    P,P′-(2,5-Dihydroxy-3,6-dimethyl-2,5-dioxo-2λ5,5λ5-[1,4,2,5]-dioxadiphosphinan-2,5-diyl)-bis-phosphonsäure (1994)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 620 (1994), S. 1799-1804 
    Details
    ISSN: 0044-2313
    Keywords: 1,4,2λ5,5λ5-Dioxadiphosphorinane ; NMR spectra ; Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: P,P′-(2,5-Dihydroxy-3,6-dimethyl-2,5-dioxo-2λ5,5λ5-[1,4,2,5]dioxadiphosphinane-2,5-diyl)-bis-phosphonic AcidThe tetrahydrate 1 of the title compound crystallizes in the monoclinic space group P21/c with a = 845.8, b = 1 098, c = 981.7 pm, β = 113.02° and Z = 2. The anions of the oxonium compound (H3O+ · H2O)2(C4H10O12P42-) are layered by hydrogen bridges. The 1H, 13C and 31P NMR spectra (4 and 5 spin systems) are discussed.
    Notes: C4H12O12P4 · 4 H2O (1), das Tetrahydrat der Titelverbindung, kristallsiert monoklin in der Raumgruppe P21/c mit a = 845,8, b = 1 098, c = 981,7 pm, β = 113,02° und Z = 2. 1 liegt als Oxoniumsalz (H3O+ · H2O)2(C4H10O12P42-) vor, in dem die Anionen über H-Brücken zu Schichten verknüpft sind. Die 4- und 5-Spinsysteme der 1H-, 13C- und 31P-NMR-Spektren werden detailliert analysiert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19946201023
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