ISSN:
1572-8943
Keywords:
copper thiocarbamide complex
;
DTA
;
spray pyrolysis
;
TG
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Hydrated isostructural 1:3 complexes of copper(I) chloride and bromide with thiourea were synthesised and their thermal decomposition studied by simultaneous TG/DTA complemented by ex situ FTIR and XRD studies. The decomposition of Cu(tu)3Cl·H2O is initiated by dehydration around 100°C, followed by a total multi-step degradation of the structure in the temperature range of 200–600°C. The counter ion has some influence on the temperatures and composition of the solid residue. The results were compared with those obtained with the 1:1 complex Cu(tu)Cl·1/2H2O.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1010184107901
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