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  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Catalysis letters 16 (1992), S. 407-412 
    ISSN: 1572-879X
    Schlagwort(e): CH x species ; carbide ; methanation ; hydrogenation ; nickel
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract The CH x species formed on Ni(100) by hydrogenation of carbidic carbon have been detected using high resolution electron energy-loss spectroscopy (HREELS). Exposures of carbidic carbon to 1×10−7 Torr H2 and D2 at 313 K for 20 min produce CH x and CD x species, respectively. These species are identified by two energy-loss peaks for CH x at 2970 and 1380 cm−1 and only one peak for CD x at 1980 cm−1. Because of the existence of the intense peak at 1380 cm−1, in the range of a scissors mode for CH2 and a symmetric deformation mode for CH3, the CH x species are tentatively ascribed to CH2 and/or CH3. The CD x species undergo decomposition at 330–370 K in UHV as well as in hydrogen below 10−7 Torr. No stable CH x species are observed above 400 K, which is lower than the normal reaction temperature of the methanation reaction (500 K).
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Landscape ecology 15 (2000), S. 591-601 
    ISSN: 1572-9761
    Schlagwort(e): adjacency probability ; aggregation index ; AI ; contagion index ; landscape indices ; map resolution ; measurement resolution ; shape index ; spatial pattern
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie
    Notizen: Abstract There is often need to measure aggregation levels of spatial patterns within a single map class in landscape ecological studies. The contagion index (CI), shape index (SI), and probability of adjacency of the same class (Qi), all have certain limits when measuring aggregation of spatial patterns. We have developed an aggregation index (AI) that is class specific and independent of landscape composition. AI assumes that a class with the highest level of aggregation (AI =1) is comprised of pixels sharing the most possible edges. A class whose pixels share no edges (completely disaggregated) has the lowest level of aggregation (AI =0). AI is similar to SI and Qi, but it calculates aggregation more precisely than the latter two. We have evaluated the performance of AI under varied levels of (1) aggregation, (2) number of patches, (3) spatial resolutions, and (4) real species distribution maps at various spatial scales. AI was able to produce reasonable results under all these circumstances. Since it is class specific, it is more precise than CI, which measures overall landscape aggregation. Thus, AI provides a quantitative basis to correlate the spatial pattern of a class with a specific process. Since AI is a ratio variable, map units do not affect the calculation. It can be compared between classes from the same or different landscapes, or even the same classes from the same landscape under different resolutions.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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