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Chemical reactivity of CO and CO2 at a Cu(110)-Cs surface (1994)

Carley, A. F. ; Roberts, M. W. ; Strutt, A. J.

Springer

Catalysis letters 29 (1994), S. 169-175

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ISSN: 1572-879X

Keywords: carbon dioxide ; carbon monoxide ; cesium ; copper ; electron spectroscopy

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract Carbon dioxide and carbon monoxide undergo reactive chemisorption with cesium modified Cu(110) and Cu(110)-O surfaces and via the anionic intermediate CO 2 δ− (a) form a surface carbonate. The CO 2 δ− (a) species was characterised by VEELS and XPS at low temperature (80 K) and the surface carbonate at 295 K. For cesium modified Cu(110) surfaces chemisorption of carbon monoxide gives rise to electron energy loss peaks (v co) as low as 1450 cm−1 at 295 K.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00814263

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