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  • Digitale Medien  (2)
  • chemotaxonomy  (2)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Journal of chemical ecology 8 (1982), S. 285-300 
    ISSN: 1573-1561
    Schlagwort(e): Monomorium spp. ; Hymenoptera ; Formicidae 2,5-dialkylpyrrolidines ; ant venom alkaloids ; methoxymercuration-demercuration ; chemotaxonomy
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract A comparative analysis of the venomous alkaloids produced by ant species in the subgenusMonomorium of the genusMonomorium has been undertaken. All species produce mixtures of unsymmetricaltrans-2,5-dialkylpyrrolidines, but the proportions of the constituents may vary considerably between species. All alkaloids contain both C6 and C9 side chains which are present as C9-saturated. C6-monounsaturated, and both C6-and C9-monounsaturated dialkylpyrrolidines. The structure of 2-(1-hex-5-enyl)-5-(1-non-8-enyl)pyrrolidine, a previously undescribed alkaloid, was proved by unambiguous synthesis after the location of the double bonds was established by the methoxymercuration-demercuration followed by mass spectrometry. The possible chemotaxonomic significance of the mixtures of venomous alkaloids produced by these species ofMonomorium is discussed.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Journal of chemical ecology 5 (1979), S. 53-62 
    ISSN: 1573-1561
    Schlagwort(e): Coreidae ; Heteroptera ; Hemiptera ; sex attractant ; pheromone ; sexual selection ; n-octanol ; benzyl alcohol ; vanillin ; 2-phenyl-ethanol ; leaf-footed bugs ; chemotaxonomy ; allomome
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Chemie und Pharmazie
    Notizen: Abstract The 7–8th ventral abdominal gland secretions from 6 adult male leaf-footed bugs,Leptoglossus spp., and a related species,Euthochtha galeator, were chemically analyzed by GC-MS. Of the 11 volatile compounds identified, all but one of the compounds (n-octanol) were aromatic, including compounds with the familiar odors of cherries, vanilla, cinnamon, and roses. The preponderance of aromatics in the adult male ventral abdominal gland secretions contrasts sharply with the aliphatic compounds which comprise the metathoracic gland defensive secretions of adult males and females. Also, the male-specific secretions are species-specific, both qualitatively and quantitatively, whereas the metathoracic gland secretions of Coreoidea are only distinctive at the generic level. It is proposed that males were favored as the emitters of attractive signals by sexual selection, whereas the specificity of the signal is the result of natural selection against hybridization.
    Materialart: Digitale Medien
    Bibliothek Standort Signatur Band/Heft/Jahr Verfügbarkeit
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