ISSN:
0268-2605
Keywords:
Triorganotin
;
carboxylate
;
crystal structure
;
fungitoxicity
;
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The [nBu3Sn(N-phthaloylglycinate)(OH2)] compound has been prepared and characterized. The crystal structure reveals the tin atom, in each of the two molecules comprising the asymmetric unit, to exist in a distorted trigonal bipyramidal geometry in which the trigonal plane is defined by the three organic substituents and the axial sites are occupied by an oxygen atom derived from a monodentate carboxylate ligand and a coordinated water molecule. The [nBu3Sn(N-phthaloylglycinate)(OH2)] compound and three other triorganotin derivatives of N-phthaloyl-protected amino acids display marked toxicity against several economically important plant pathogenic fungi.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aoc.590080108
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